Polynuclear Acetylides. Synthesis, Spectroscopic Features, and Structural Systematics for a Complete Triad of μ2-η2'Complexes: M2(CO)6(μ2-η2-C≡CR) (μ-PPh2) (M = Fe, Ru, Os)

Organometallics

Volumn 7, Issue 4, 1988, Pages 969-977

  Cherkas, Andrew A ^a   Randall, Leslie H ^a   MacLaughlin, Shane A ^a   Mott, Graham N ^a   Taylor, Nicholas J ^a   Carty, Arthur J ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000152499     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00094a029     Document Type: Article

References (29)

1. For a review of acetylide coordination chemistry see: Nast, R. Coord. Chem. Rev. 1982, 47, 89.
2. (a) Carty, A. J. Pure Appl. Chem. 1982, 54, 113. (b) For a comparison of bonding modes for acetylides and related ligands on clusters see: Sappa, E.; Tiripicchio, A.; Braunstein, P. Coord. Chem. Rev. 1985, 65, 219.
3. (a) Wong, Y. S.; Paik, H. N.; Chieh, P. C.; Carty, A. J. J. Chem. Soc., Chem. Commun. 1975, 309. (b) Carty, A. J.; Taylor, N. J.; Paik, H. N.; Smith, W.; Yule, J. G. J. Chem. Soc., Chem. Commun. 1976, 41. (c) Deeming, A. J.; Hasso, S. J. Organomet. Chem. 1976, 112, C39. (d) Churchill, M. R.; DeBoer, B. G.; Shapley, J. R.; Keister, J. B. J. Am. Chem. Soc. 1976, 98, 2357. (e) Henrick, K.; McPartlin, M.; Deeming, A. J.; Hasso, S.; Manning, P. J. Chem. Soc., Dalton Trans. 1982, 899. (f) Mott, G. N.; Carty, A. J. Inorg. Chem. 1983, 22, 2726 and references therein.
4. (a) Bell, R. A.; Chisholm, M. H. Inorg. Chem. 1977, 16, 687. (b) Bruce, M. I.; Swincer, A. G. Adv. Organomet. Chem. 1983, 22, 59 and references therein. (c) Bruce, M. I.; Wallis, R. C. J. Organomet. Chem. 1978, 161, Cl. (d) Davison, A.; Selegue, J. P. J. Am. Chem. Soc. 1978, 100, 7763. (e) Berke, H. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1980, 35B, 86. (f) Carty, A. J.; Taylor, N. J.; Sappa, E.; Tiripicchio, A. Inorg. Chem. 1983, 21, 1871. (g) Hriljac, J. A., Shriver, D. F. Organometallics 1985, 4, 2225. (h) Mays, A.; Schaefer, K. C.; Huang, E. Y. J. Am. Chem. Soc. 1984, 106, 1517. (i) Sebald, A.; Wrackmeyer, B. J. Chem. Soc., Chem. Commun. 1983, 1293.
5. See ref 4 and also: Kostic, N. M.; Fenske, R. F. Organometallics 1982, 1, 974.
6. (a) For an earlier review of our work in this area see: Fehlhammer, W. P.; Stolzenberg, H. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1982; Vol. 4, Chapter 31, pp 513–613. (b) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1984, 3, 177. (c) Nucciarone, D.; MacLaughlin, S. A.; Taylor, N. J.; Carty, A. J. Organometallics 1988, 7, 106.
7. Carty, A. J.; Hota, N. K.; Ng, T. W.; Patel, H. A.; O'Connor, T. J. Can. J. Chem. 1971, 2706.
8. Bruce, M. I.; Kehoe, D. C.; Matisons, J. G.; Nicholson, B. K.; Rieger, P. H.; Williams, M. L. J. Chem. Soc., Chem. Commun. 1982, 442.
9. Johnson, B. F. G.; Lewis, J.; Pippard, D. A. J. Chem. Soc., Dalton Trans. 1981, 407.
10. Carty, A. J.; MacLaughlin, S. A.; Taylor, N. J. J. Organomet. Chem. 1981, 204, C27.
11. (a) International Tables for X-ray Crystallography; Kynoch: Birmingham, England, 1974; Vol. 4. (b) Stewart, R. F.; Davidson, E. R.; Simpson, W. T. J. Chem. Phys. 1965, 42, 3175.
12. Carty, A. J.; Mott, G. N.; Taylor, N. J.; Yule, J. E. J. Am. Chem. Soc. 1978, 100, 3051.
13. Patel, H. A.; Fischer, R. G.; Carty, A. J.; Naik, D. V.; Palenik, G. J. J. Organomet. Chem. 1973, 60, C49.
14. Smith, W. R.; Yule, J.; Taylor, N. J.; Paik, H. N.; Carty, A. J. Inorg. Chem. 1977, 16, 1593.
15. Carty, A. J.; Smith, W. F.; Taylor, N. J. J. Organomet. Chem. 1978, 146, Cl.
16. (a) Van Gastel, F.; MacLaughlin, S. A.; Lynch, M.; Carty, A. J.; Sappa, E.; Tiripicchio, A.; Tiripicchio-Camellini, M. J. Organomet. Chem. 1987, 326, C65. (b) For an earlier review of P-C cleavage see: Garrou, P. E. Chem. Rev. 1985, 85, 171.
17. (a) Carty, A. J. Adv. Chem. Ser. 1982, No. 196, 163. (b) Carty, A. J.; MacLaughlin, S. A.; Nucciarone, D. In Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis: Organic Compounds and Metal Complexes; Verkade, J. G., Quin, L. D., Eds.; VCH Publishers: New York, 1987; Chapter 16.
18. Randall, L.; Cherkas, A. A.; Carty, A. J., submitted for publication.
19. (a) Shapley, J. R.; Richter, S. I.; Tachikawa, M.; Keister, J. B. J. Organomet. Chem., 1975, 94, C43. (b) Clauss, A. D.; Tachikawa, M.; Shapley, J. R.; Pierpont, C. G. Inorg. Chem. 1981, 20, 1528.
20. Lee, K. W.; Pennington, W. T.; Cordes, A. W.; Brown, T. L. J. Am. Chem. Soc. 1985, 107, 631.
21. (a) Rosenberg, D.; Drenth, W. Tetrahedron 1971, 27, 3893. (b) Hagens, W.; Bos, H. J. T.; Arens, J. F. Recl. Trav. Chim. Pays-Bas. 1973, 92, 762. (c) Dawson, D. A.; Reynolds, W. F. Can. J. Chem. 1975, 53, 373. (d) Pople, J. A.; Gordon, M. J. Am. Chem. Soc. 1967, 89, 4253. (e) Sichel, J. M.; Whitehead, M. A. Theor. Chim. Acta 1966, 5, 35.
22. (a) De Montauzon, D.; Mathieu, R. J. Organomet. Chem. 1983, 252, C83. (b) Green, M.; Marsden, K.; Salter, I. D.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Chem. Commun. 1983, 446. (c) Aime, S.; Gambino, O.; Milone, L.; Sappa, E.; Rosenberg, E. Inorg. Chim. Acta 1975, 15, 53. For reviews see ref 2b and also: Mann, B. E. Adv. Organomet. Chem. 1974, 12, 135.
23. 24c' the unbridged M-M bond lengths average 2.673, 2.8542, and 2.877 Å, respectively. These values can be taken as representative of M-M single bond distances. (a) Wei, C. H.; Dahl, L. F. J. Am. Chem. Soc. 1969, 91, 1351. (b) Churchill, M. R.; Hollander, F. J.; Hutchinson, J. P. Inorg. Chem. 1977, 16, 2655. (c) Churchill, M. R.; DeBoer, B. G. Inorg. Chem. 1977, 16, 878.
24. Taylor, N. J.; Mott, G. N.; Carty, A. J. Inorg. Chem. 1980, 19, 560.
25. Mott, G. N.; Granby, R.; MacLaughlin, S. A.; Taylor, N. J.; Carty, A. J. Organometallics 1983, 2, 189.
26. Geoffroy, G. L.; Rosenberg, S.; Herlinger, A. W.; Rheingold, A. L. Inorg. Chem. 1986, 25, 2916.
27. Cowie, M. R.; Loeb, S. A. Organometallics 1985, 4, 852.
28. Ciriano, M.; Howard, J. A. K.; Spencer, J. L.; Stone, F. G. A.; Wadepohl, H. J. Chem. Soc., Dalton Trans. 1979, 1749.
29. (a) Hutton, A. T.; Langrick, R. C.; McEwan, D. M.; Pringle, P. G.; Shaw, B. L. J. Chem. Soc., Dalton Trans. 1985, 2121. (b) Salah, O. M. A.; Bruce, M. I.; Churchill, M. R.; DeBoer, B. G. J. Chem. Soc., Chem. Commun. 1974, 688. (c) Yasufuku, K.; Yamazaki, H. Bull Chem. Soc. Jpn. 1972, 45, 2664.