Rates and Mechanism of the Formation of Zerovalent Palladium Complexes from Mixtures of Pd(OAc)2 and Tertiary Phosphines and Their Reactivity in Oxidative Additions

Organometallics

Volumn 14, Issue 4, 1995, Pages 1818-1826

  Amatore, Christian ^a   Carré, Emmanuelle ^a   Jutand, Anny ^a   M'Barki, Mohamed Amine ^b   Kneisel, Boris O ^c   Herbst Irmer, Regine ^c   Pellinghelli, Maria Angela ^d   Tiripicchio, Antonio ^d  

^a ECOLE NORMALE SUPÉRIEURE   (France)

^b IBN TOFAIL UNIVERSITY   (Morocco)

^c UNIVERSITY OF GÖTTINGEN   (Germany)

^d CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000151617     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00004a039     Document Type: Article

References (18)

1. Evidence for the ligation of the palladium(0) complex by an acetate anion and its consequences on the rate of oxidative addition will be published later: Amatore, C.; Carré, E.; Jutand, A.; M'Barki, M. A.; Meyer, G. Unpublished results (1994), manuscript in preparation.
2. Benson, S. W. The Foundations of Chemical Kinetics; McGraw-Hill Book Co. Inc.: New York, Toronto, London, 1960; p 33.
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7. 2(RCN) (R = Ph or Me) into metallic palladium. See: McCrindle. R.; Ferguson, G.; Arsenault, G. J.; McAllees, A. J.; Stephenson, D. K. J. Chem. Res. Synop. 1984, 360.
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12. -have been reported as intermediates in oxidative additions. See: Amatore, C.; Jutand, A.; Suarez, A. J. Am. Chem. Soc. 1993, 115, 9531.
13. As observed in preliminary studies involving different bivalent palladium salts with oxygenated and nonoxygenated anions: Amatore, C.; Jutand, A.; M'Barki, M. A. Unpublished results (1994).
14. Amatore, C.; Jutand, A.; Medeiros, M. J. Unpublished results (1994), manuscript in preparation.
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