Solution Studies of Ru2(O2CR)4n+ Complexes (n = 0, 1; O2CR = Octanoate, Crotonate, Dimethylacrylate, Benzoate, p-Toluate) and Solid-State Structures of Ru2(O2C-p-tolyl) 4(THF)2,[Ru2(O2C-p-tolyl) 4(THF)2]+[BF4]-,

Inorganic Chemistry

Volumn 35, Issue 12, 1996, Pages 3643-3658

  Chisholm, Malcolm H ^a   Christou, George ^a   Folting, Kirsten ^a   Huffman, John C ^a   James, Chris A ^b   Samuels, John A ^c   Wesemann, Jodi L ^d   Woodruff, William H ^b  

^a INDIANA UNIVERSITY   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

^c Watkins Johnson Company   (United States)

^d HARVEY MUDD COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000142327     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950860u     Document Type: Article

References (107)

1. Cotton, F. A.; Rice, C. E.; Rice, G. W. J. Am. Chem. Soc. 1977, 99, 4704.
2. (a) Cotton, F. A.; Daniels, L. M.; Kibala, P. A.; Matusz, M.; Roth, W. J.; Schwotzer, W.; Wang, W.; Zhong, B. Inorg. Chim. Acta 1994, 215, 9.
3. (b) Martin, D. S.; Hueng, H.-W. Inorg. Chem. 1990, 29, 3674.
4. (c) Cotton, F. A.; Mester, Z. C.; Webb, T. R. Acta Crystallogr. 1974, B30, 2768.
5. (a) Baxter, D. V.; Cayton, R. H.; Chisholm, M. H.; Huffman, J. C.; Putilina, E. F.; Tagg, S. L.; Wesemann, J. L.; Zwanziger, J. W.; Darrington, F. D. J. Am. Chem. Soc. 1994, 116, 4551.
6. (b) Chisholm, M. H.; Chiu, H. T.; Huffman, J. C. Polyhedron 1984, 3, 759.
7. (a) Bennett, M. J.; Caulton, K. G.; Cotton, F. A. Inorg. Chem. 1969, 8, 1.
8. (b) Bino, A.; Cotton, F. A.; Felthouse, T. R. Inorg. Chem. 1979, 18, 2599.
9. (c) Martin, D. S.; Newman, R. A.; Vlasnik, L. M. Inorg. Chem. 1980, 19, 3404.
10. (d) Drew, M. G. B.; Higgins, P.; McCann, G. M. J. Chem. Soc., Chem. Commun. 1987, 1385.
11. (e) Higgins, P.; McCann, G. M. J. Chem. Soc., Dalton Trans. 1988, 661.
12. (f) Cotton, F. A.; Matusz, M.; Zhong, B. Inorg. Chem. 1988, 27, 4368.
13. (g) McCann, M.; Carvill, A.; Guinan, P.; Higgins, P.; Campbell, J.; Ryan, H.; Walsh, M. Polyhedron 1991, 10, 2273.
14. (h) McCann, M.; Carvill, A.; Cardin, C.; Convery, M. Polyhedron 1993, 12, 1163.
15. (i) Cotton, F. A.; Kim, Y.; Ren, T. Polyhedron 1993, 12, 607.
16. (a) Lindsay, A. J.; Wilkinson, G.; Motevalli, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1987, 2723.
17. (b) Lindsay, A. J.; Wilkinson, G.; Motevalli, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1985, 2321.
18. (c) Lindsay, A. J.; Tooze, P. R.; Motevalli, M.; Hursthouse, M. B.; Wilkinson, G. J. Chem. Soc., Chem. Commun. 1984, 1383.
19. (d) Cotton, F. A.; Miskowski, V. M.; Zhong, B. J. Am. Chem. Soc. 1989, 111, 6177.
20. (a) Das, B. K.; Chakravarty, A. R. Polyhedron 1991, 10, 491.
21. (b) Spohn, M.; Strähle, J.; Hiller, W. Z. Naturforsch. 1986, 41B, 541.
22. (a) Cotton, F. A.; Shiu, K.-B. Rev. Chim. Miner. 1986, 23, 14.
23. (b) Reference 2a.
24. (a) Campbell, G. C.; Haw, J. F. Inorg. Chem. 1988, 27, 3706.
25. (b) Lomer, T. R.; Perera, K. Acta Crystallogr. 1974, B30, 2912.
26. (c) Lomer, T. R.; Perera, K. Acta Crystallogr. 1974, B30, 2913.
27. 2a was shown recently by single-crystal X-ray diffraction to have no axial interactions.
28. Cotton, F. A.; Walton, R. A. Multiple Bonds between Metal Atoms, 2nd ed.; Clarendon Press: Oxford, U.K., 1993; p 18.
29. Cotton, F. A.; Feng, X.; Kibala, P. A.; Matusz, M. J. Am. Chem. Soc. 1988, 110, 2807 and references therein.
30. Hall, M. B. Polyhedron 1987, 6, 670 and references therein.
31. Hao, S.; Edema, J. H. H.; Gambarotta, S.; Bensimon, C. Inorg. Chem. 1992, 31, 2676 and references therein.
32. (a) Marchon, J.-C.; Maldivi, P.; Giroud-Godquin, A.-M.; Guillon, D.; Skoulios, A.; Strommen, D. P. Phil. Trans. R. Soc. London A 1990, 330, 109.
33. (b) Maldivi, P.; Giroud-Godquin, A.-M.; Marchon, J.-C.; Guillon, D.; Skoulios, A. Chem. Phys. Lett. 1989, 157, 552.
34. (a) Stephenson, T. A.; Wilkinson, G. J. Inorg. Nucl. Chem. 1966, 28, 2285.
35. (b) Mukaida, M.; Nomura, T.; Ishimori, T. Bull. Chem. Soc. Jpn. 1972, 45, 2143.
36. (c) Cotton, F. A.; Pedersen, E. Inorg. Chem. 1975, 14, 388.
37. Telser, J.; Drago, R. S. Inorg. Chem. 1984, 23, 3114.
38. (a) Quelch, G. E.; Hillier, I. H.; Guest, M. F. J. Chem. Soc., Dalton Trans. 1990, 3075.
39. (b) Clark, D. L.; Green, J. C.; Redfern, C. M. J. Chem. Soc., Dalton Trans. 1989, 1037.
40. (c) Clark, D. L.; Green, J. C.; Redfern, C. M.; Quelch, G. E.; Hillier, I. H.; Guest, M. F. Chem. Phys. Lett. 1989, 154, 326.
41. Bonnet, L.; Cukiernik, F. D.; Maldivi, P.; Giroud-Godquin, A.-M.; Marchon, J.-C; Ibn-Elhaj, M.; Guillon, D.; Skoulios, A. Chem. Mater. 1994, 6, 31.
42. Norman, J. G., Jr.; Renzoni, G. E.; Case, D. A. J. Am. Chem. Soc. 1979, 101, 5256.
43. (a) Cotton, F. A.; Ren, T.; Eglin, J. L. Inorg. Chem. 1991, 30, 2552.
44. (b) Cotton, F. A.; Ren, T.; Eglin, J. L. J. Am. Chem. Soc. 1990, 112, 3439.
45. (c) Cotton, F. A.; Feng, X. Inorg. Chem. 1989, 28, 1180.
46. (d) Cotton, F. A.; Matusz, M. J. Am. Chem. Soc. 1988, 110, 5761.
47. (e) Chakravarty, A. R.; Cotton, F. A.; Tocher, D. A.; Tocher, J. H. Polyhedron 1985, 4, 1475.
48. Wesemann, J. L.; Chisholm, M. H. Submitted.
49. Historically, paramagnetic NMR data were reported so that the sign of the chemical shift corresponded to the field (upfield shifts were positive). In this report, the current standard convention is used (upfield shifts are negative). The equations stated here correspond to this convention.
50. Cotton, F. A.; Daniels, L. M.; Kibala, P. A. Inorg. Chem. 1992, 31, 1865.
51. Moodley, K. G.; Chisholm, M. H. Unpublished results.
52. Cotton, F. A.; Ilsley, W. H.; Kaim, W. J. Am. Chem. Soc. 1980, 102, 3475.
53. Satterlee, J. D. Concepts Magn. Reson. 1990, 2, 69.
54. Drago, R. S. Physical Methods in Chemistry; W. B. Saunders Co.: Philadephia, 1977; Chapter 12.
55. Drago, R. S.; Zink, J. I.; Richman, R. M.; Perry, W. D. J. Chem. Educ. 1974, 51, 371, 464.
56. -, indicated by the increased intensity of the signal at -39 ppm.
57. Drago, R. S.; Cosmano, R.; Telser, J. Inorg. Chem. 1984, 23, 4514.
58. As reported in ref 26, the equation predicts the incorrect sign for Fe(III) porphyrin systems (see Supporting Information). The omission of the minus sign has been corrected in the equation reported here.
59. Collman, J. P.; Barnes, C. E.; Swepston, P. N.; Ibers, J. A. J. Am. Chem. Soc. 1984, 106, 3500.
60. Morishima, I.; Okada, K.; Yonezawa, T.; Goto, K. J. Am. Chem. Soc. 1971, 93, 3922.
61. (a) La Mar, G. N.; Eaton, G. R.; Holm, R. H.; Walker, F. A. J. Am. Chem. Soc. 1973, 95, 63.
62. (b) Bertini, I.; Luchinat, C.; Messori, L.; Vašák, M. J. Am. Chem. Soc. 1989, 111, 7300.
63. (c) Banci, L.; Bertini, I.; Briganti, F.; Luchinat, C. New J. Chem. 1991, 15, 467.
64. (a) Wüthrich, K. Struct. Bonding 1970, 8, 53.
65. (b) Horrocks, W. DeW., Jr.; Greenberg, E. S. Mol. Phys. 1974, 27, 993.
66. (a) Chmielewski, P. J.; Latos-Graźyński, L. Inorg. Chem. 1992, 31, 5231.
67. (b) Latos-Graźyński, L. Inorg. Chem. 1985, 24, 1681.
68. (c) Reference 34a.
69. (d) Behere, D. V.; Birdy, R.; Mitra, S. Inorg. Chem. 1982, 21, 386.
70. Kurland, R. J.; McGarvey, B. R. J. Magn. Reson. 1970, 2, 286. Please note that the signs of the equations taken from this article have been switched to correspond to the convention used here.
71. Horrocks, W. DeW., Jr. In NMR of Paramagnetic Molecules: Principles and Applications; La Mar, G. N., Horrocks, W. DeW., Holm, R. H., Eds.; Academic Press: New York, 1973; Chapter 4.
72. Miskowski, V. M.; Gray, H. B. Inorg. Chem. 1988, 27, 2501.
73. Miskowski, V. M.; Loehr, T. M.; Gray, H. B. Inorg. Chem. 1987, 26, 1098.
74. Chisholm, M. H.; Clark, D. L.; Huffman, J. C.; Van Der Sluys, W. G.; Kober, E. M.; Lichtenberger, D. L.; Bursten, B. E. J. Am. Chem. Soc. 1987, 109, 6796.
75. Ketteringham, A. P.; Oldham, C. J. Chem. Soc., Dalton Trans. 1973, 1067.
76. (a) Clark, R. J. H.; Franks, M. L. J. Chem. Soc., Dalton Trans. 1976, 1825.
77. (b) Clark, R. J. H.; Ferris, L. T. H. Inorg. Chem. 1981, 20, 2759.
78. (c) Miskowski, V. M.; Loehr, T. M.; Gray, H. B. Inorg. Chem. 1988, 27, 4708.
79. Pauling electronegativities: Rh, 2.28; Ru, 2.2; Mo(II), 2.16. From: Huheey, J. E.; Keiter, E. A.; Keiter, R. L. Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed.; Harper Collins: New York, 1993.
80. Kawamura, T.; Katayama, H.; Nishikawa, H.; Yamabe, T. J. Am. Chem. Soc. 1989, 111, 8156.
81. (a) Drago, R. S.; Cosmano, R.; Telser, J. Inorg. Chem. 1984, 23, 3120.
82. (b) Kawamura, T.; Fukamachi, K.; Sowa, T.; Hayashida, S.; Yonezawa, T. J. Am. Chem. Soc. 1981, 103, 364.
83. (c) Kawamura, T.; Fukamachi, K.; Hayashida, S. J. Chem. Soc., Chem. Commun. 1979, 945.
84. San Filippo, J., Jr.; Sniadoch, H. J. Inorg. Chem. 1976, 15, 2209.
85. (a) M = Cr, R = Ph, ∠ = 6.0°: Cotton, F. A.; Extine, M. W.; Rice, G. W. Inorg. Chem. 1978, 17, 176.
86. (b) M = Mo, R = Ph, ∠ = 7.2°: Collins, D. M.; Cotton, F. A.; Murillo, C. A. Inorg. Chem. 1976, 15, 2950.
87. (c) M = W, R = Ph, ∠ = 10.7°: Cotton, F. A.; Wang, W. Inorg. Chem. 1984, 23, 1604.
88. (d) M = Co, R = Ph, ∠ = 5.9°: Davies, J. E.; Rivera, A. V.; Sheldrick, G. M. Acta Crystallogr. 1977, B33, 156.
89. (e) M = Rh, R = Ph, ∠ = 1.2°: Simmons, C. J.; Clearfield, A.; Sun, Y. Inorg. Chim. Acta 1986, 121, L3.
90. (f) M = Cu, R = Ph, ∠ = 4.5°: Speier, G.; Fülöp, V. J. Chem. Soc., Dalton Trans. 1989, 2331.
91. 5Ph, ∠ = 45°: Cotton, F. A.; Thompson, J. L. Inorg. Chem. 1981, 20, 1292.
92. 5Ph, ∠ = 48°: Cotton, F. A.; Thompson, J. L. Inorg. Chem. 1981, 20, 3887.
93. 3Ph, ∠ = 42°: ref 48c.
94. 5, ∠ = 74°: Cotton, F. A.; Thompson, J. L. Inorg. Chim. Acta 1984, 81, 193.
95. (e) M = Cu, R = 2,6-MeO-Ph, ∠ = 58°: Erre, L. S.; Micera, G.; Piu, P.; Cariati, F.; Ciani, G. Inorg. Chem. 1985, 24, 2297.
96. 4 units were present in the crystal.
97. Storhoff, B. N.; Lewis, H. C., Jr. Coord. Chem. Rev. 1977, 23, 1.
98. Arafa, I. M.; Goff, H. M.; David, S. S.; Murch, B. P.; Que, L., Jr. Inorg. Chem. 1987, 26, 2779.
99. (a) Marchon, J.-C.; Maldivi, P. Private communication.
100. (b) Mitchell, R. W.; Spencer, A.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1973, 846.
101. Rempel, G. A.; Legzdins, P.; Smith, H.; Wilkinson, G. Inorg. Synth. 1972, 13, 90.
102. Brignole, A. B.; Cotton, F. A. Inorg. Synth. 1972, 13, 81.
103. (a) Rose, D.; Wilkinson, G. J. Chem. Soc. A 1970, 1791.
104. (b) Gilbert, J. D.; Rose, D.; Wilkinson, G. J. Chem. Soc. A 1970, 2765.
105. Barral, M. C.; Jiménez-Aparicio, R.; Rial, C.; Royer, E.; Saucedo, M. J.; Urbanos, F. A. Polyhedron 1990, 9, 1723.
106. Evans, D. F. J. Chem. Soc. 1959, 2003.
107. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Kirkpatrick, C. C. Inorg. Chem. 1984, 23, 1021.