Coordination of olefins and N-donor ligands at the fragment [2,6-bis((diphenylphosphino)methyl)pyridine]-palladium(II). Synthesis, structure, and amination of the new dicationic complexes [Pd(PNP)(CH2=CHR)](BF4)2 (R = H, Ph)

Organometallics

Volumn 17, Issue 10, 1998, Pages 2060-2066

  Hahn, Christine ^a   Vitagliano, Aldo ^b   Giordano, Federico ^b   Taube, Rudolf ^c  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^c TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000140101     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970699q     Document Type: Article

References (32)

1. (a) Krukowka, E.; Taube, R.; Steinborn, D. Ger. Offen. 296 909 A5 (10.11.88), 1991; Chem. Abstr. 1992, 116, 213993h.
2. (a) Krukowka, E.; Taube, R.; Steinborn, D. Ger. Offen. 296 909 A5 (10.11.88), 1991; Chem. Abstr. 1992, 116, 213993h.
3. (b) Taube, R. In Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B.., Herrmann, W. A., Eds.; Verlag Chemie: Weinheim, Germany, 1996; Vol. 1, p 507.
4. Hahn, C.; Sieler, J.; Taube, R. Chem. Ber. 1997, 130, 939.
5. Hahn, C.; Sieler, J.; Taube, R. Polyhedron 1998, in press.
6. A stepwise catalytic cycle, involving N-H activation rather than nucleophilic attack, was obtained in the Ir-promoted amination of norbornene. See: Casalnuovo, A. L.; Calabrese, J. C.; Milstein, D. J. Am. Chem. Soc. 1988, 110, 6738.
7. (a) Panunzi, A.; De Renzi, A.; Palumbo, R.; Paiaro, G. J. Am. Chem. Soc. 1969, 91, 3879.
8. (b) Panunzi, A.; De Renzi, A.; Paiaro, G. J. Am. Chem. Soc. 1970, 92, 3488.
9. (c) Gasc, M.; Lattes, A.; Perie, J. J. Tetrahedron 1983, 39, 703-731.
10. (d) Young, G. B. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: London, 1995; Vol. 9, pp 533-588.
11. (a) A°kermark, B.; Bäckvall, J.-E.; Hegedus, L. S.; Zetterberg, K.; Siirala-Hansén, K.; Sjöberg, K. J. Organomet. Chem. 1974, 72, 127.
12. (b) Akermark, B.; Bäckvall, J.-E.; Siirala-Hansén, K.; Sjöberg, K.; Zetterberg, K. Tetrahedron Lett. 1974, 1363.
13. (c) Akermark, B.; Bäckvall, J.-E.; Zetterberg, K. Acta Chem. Scand. 1982, B36, 577-585.
14. (d) Davies, J. A. in Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: London, 1995; Vol. 9, pp 293-316.
15. Steffey, B. D.; Miedaner, A.; Maciejewski-Farmer, M. L.; Bernatis, P. R.; Herring, A. M.; Allured, V. S.; Carperos, V.; DuBois, D. L. Organometallics 1994, 13, 4844.
16. Vasapollo, G.; Nobile, C. F.; Sacco, A. J. Organomet. Chem. 1985, 296, 435-441.
17. Storhoff, B. N.; Lewis, H. C. Coord. Chem. Rev. 1977, 23, 1.
18. Dahlhoff, W. V.; Nelson, S. M. J. Chem. Soc. (A) 1971, 2184.
19. Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405.
20. Kurosawa, H.; Majima, T.; Asada, N. J. Am. Chem. Soc. 1980, 102, 6996 and references therein.
21. Albright, T. A.; Hoffmann, R.; Thibeault, J. C.; Thorn, D. L. J. Am. Chem. Soc. 1979, 101, 3801.
22. Miki, K.; Shiotani, O.; Kai, Y.; Kasai, N.; Kanatani, H.; Kurosawa, H. Organometallics 1983, 2, 585.
23. Nyburg, S. C.; Simpson, K.; Wong-Ng, W. J. Chem. Soc., Dalton Trans. 1976, 1865.
24. Green, M.; Sarhan, J. K. K.; Al-Najjar, I. M. J. Chem. Soc., Dalton Trans. 1981, 1565.
25. Annibale, G.; Maresca, L.; Natile, G.; Tiripicchio, A.; Tiripicchio Camellini, M. J. Chem. Soc., Dalton Trans. 1982, 1587.
26. Sakaki, S.; Maruta, K.; Ohkubo, K. Inorg. Chem. 1987, 26, 2499.
27. De Renzi, A.; Paiaro, G.; Panunzi, A.; Paolillo, L. Gazz. Chim. Ital. 1972, 102, 281.
28. (a) Bäckvall, J.-E.; Björkman, E. E. Acta Chem. Scand. 1984, B38, 91.
29. (b) Åkermark, B.; Vitagliano, A. Organometallics 1985, 4, 1275.
30. Walker, N.; Stuart, D. Acta Crystallogr., Sect. A 1983, 39, 158.
31. Enraf-Nonius CAD-4 Software, Version 5.0; Enraf-Nonius, Delft, The Netherlands, 1989.
32. von Braun, J. Chem. Ber. 1910, 43, 3209.