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For reviews see refs 2-4.
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Horspool, W. M., Song, P.-S., Eds.; CRC Press: Boca Raton, FL
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Rigaudy, J. In CRC Handbook of Organic Photochemistry and Photobiology; Horspool, W. M., Song, P.-S., Eds.; CRC Press: Boca Raton, FL, 1994; pp 325-334.
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37049087318
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Both GC-MS and HPLC studies show the occurrence of three products; the major one (ca. 90%) was confirmed to be 2 by NMR. On the basis of the literature (Pan, X.; Schuchmann, M.; Sonntag, C. J. Chem. Soc., Perkin Trans. II 1993, 289) we assume the minor products may be the corresponding 1,4-cyclohexadiene and an endoperoxide.
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Schuchmann, M.2
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22
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85034275638
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note
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The addition of para-alkyl substituents will impart even greater heats of reaction than those predicted in eqs 6 and 7 since the products will be more stabilized than the parent benzene.
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24
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0000544337
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Kochi, J. K., Ed.
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O'Neal, H. E.; Benson, S. W. In Free Radicals; Kochi, J. K., Ed., 1973; p 275.
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Benson, S.W.2
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37049089022
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Schuchmann, M.N.2
Von Sonntag, C.3
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27
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0000268984
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The hydroperoxyl radical has been shown to be a major chain carrier in related reactions: Howard, J. A.; Ingold, K. U. Can. J. Chem. 1967, 46, 785.
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Ingold, K.U.2
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28
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85034294611
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Private communication
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Farid, S. Private communication.
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Farid, S.1
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31
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85034306638
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note
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-1. In none of the experiments where we observe the anion radical of 1 do we detect any spectral shifts which would be consistent with its decay by processes other than return electron transfer.
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34
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85034277200
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note
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.2-H.
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