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Volumn 35, Issue 3, 1996, Pages 604-613

Phosphine-Based Platinum(II) Hydroxo and Oxo Complexes

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EID: 0000125489     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950593s     Document Type: Article
Times cited : (85)

References (84)
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    • note
    • 2bpy = 4,4′-di-tert-butyl-2,2′-bipyridine.
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    • 4).
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    • We thank Professor Odile Eisenstein for this suggestion
    • We thank Professor Odile Eisenstein for this suggestion.
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    • Analogous deprotonations of amido complexes have also been reported. See: (a) ref 3
    • Analogous deprotonations of amido complexes have also been reported. See: (a) ref 3. (b) Glueck, D. S.; Wu, J.; Hollander, F. J., Bergman, R. G. J. Am. Chem. Soc. 1991, 113, 2041-2054. (c) Kolel-Veetil, M. K.; Ahmed, K. J. Inorg. Chem. 1994, 33, 4945-4949.
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    • Unpublished results
    • We have observed such reactions with Au(I) hydroxo complexes. Yang, Y.; Sharp, P. R. Unpublished results.
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    • For the Rh and Ir A-frame hydroxo complexes, we found that the CO ligand IR bands are sensitive to deprotonarion of the OH group
    • For the Rh and Ir A-frame hydroxo complexes, we found that the CO ligand IR bands are sensitive to deprotonarion of the OH group.
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    • and previous papers in a series
    • This is equivalent to viewing the oxo complex 3 as a bidentate ligand. The sulfido analog of 3 has been similarly viewed and was used to prepare a series of "coordination complexes": Gilmour, D.; Luke, M. A.; Mingos, D. M. P. J. Chem. Soc., Dalton Trans. 1987, 335-340 and previous papers in a series.
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    • 4. These results will be reported in a future publication.
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