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Volumn 12, Issue 2, 1996, Pages 276-292

Macroemulsion stability: The oriented wedge theory revisited

Author keywords

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Indexed keywords


EID: 0000123276     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la950359e     Document Type: Article
Times cited : (318)

References (99)
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    • Smith, D. H.; Covatch, G. C.; Lim, K. H. J. Phys. Chem. 1991, 95, 1463. The authors also claim that they have observed a violation of the PIT rule. The surfactant concentration in their study was below the critical micelle concentration; the PIT behavior however is limited to the above-cmc concentrations; see discussion below.
    • (1991) J. Phys. Chem. , vol.95 , pp. 1463
    • Smith, D.H.1    Covatch, G.C.2    Lim, K.H.3
  • 22
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    • Thin Liquid Films: Fundamentals and Applications; Ivanov, I. B., Ed.; Marcel Dekker: New York, 1988; Vol. 29, p 1126.
    • (1988) Thin Liquid Films: Fundamentals and Applications , vol.29 , pp. 1126
  • 45
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    • Becher, P., Ed.; Marcel Dekker: New York and Basel
    • Salager, J. L. In Encyclopedia of Emulsion Technology; Becher, P., Ed.; Marcel Dekker: New York and Basel, 1983; Vol. 3; p 159.
    • (1983) Encyclopedia of Emulsion Technology , vol.3 , pp. 159
    • Salager, J.L.1
  • 48
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    • note
    • Temperature effects on the phase behavior of ionics are less pronounced and have an opposite sign.
  • 61
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    • Thesis, University of Nottingham
    • Hansrani, P. K. Thesis, University of Nottingham, 1980.
    • (1980)
    • Hansrani, P.K.1
  • 63
    • 5244356435 scopus 로고    scopus 로고
    • note
    • Phospholipids have a very low molecular solubility in water. Special care must be taken to avoid artifacts due to very slow adsorption of phospholipids at the oil-water interface, if the adsorption is accomplished from the water phase; for a detailed discussion, see ref 65.
  • 67
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    • Manuscript in preparation
    • Kabalnov, A. Manuscript in preparation.
    • Kabalnov, A.1
  • 74
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    • manuscript in preparation
    • 1/2, where φ is the volume fraction of micelles and a is the micellar radius. In this regime, the adsorption rate is proportional to the square root of the micellar concentration. The driving force of the mass transfer is still equal to the molecular solubility gradient (i.e., cmc) and is not affected by the concentration of micelles (A. Kabalnov, J. Weers, and H. Wennerström, manuscript in preparation).
    • Kabalnov, A.1    Weers, J.2    Wennerström, H.3
  • 84
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    • Kozlov, M. M.; Markin, V. S. Biofizika 1983, 28, 242. Due to geometrical similarity, the bending energy of the "stalk" joining two bilayers and the hole spanning one bilayer can be presented by essentially the same bending energy terms.
    • (1983) Biofizika , vol.28 , pp. 242
    • Kozlov, M.M.1    Markin, V.S.2
  • 92
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    • Unpublished
    • Kabalnov, A. Unpublished. See also ref 94, section 4, where the authors write: "The astonishing fact, however, is that the transition between slow and rapid phase separations takes place within a few tenths of a degree".
    • Kabalnov, A.1
  • 94
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    • note
    • If one assumes the surfactant film thickness to be constant, the value of the energy barrier becomes very sensitive to the value of the film thickness. This means that the emulsion stability pattern must be strongly dependent on the forces acting across the emulsion film. This dependence is not observed experimentally; see section 3.3. In addition, if one assumes the film thickness to be constant, both the "normal" and "inside-out" films turn out to be stable in the balanced state.
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    • Evans, D. F.; Wennerström, H. Colloidal Domain; VCH Publishers: New York-Weinheim-Cambridge, 1994; p 515.
    • (1994) Colloidal Domain , pp. 515
    • Evans, D.F.1    Wennerström, H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.