Time-Resolved Infrared Studies on Two Isomeric Ruthenium(II)/Rhenium(I) Complexes Containing a Nonsymmetric Quaterpyridine Bridging Ligand

Inorganic Chemistry

Volumn 37, Issue 10, 1998, Pages 2598-2601

  Schoonover, Jon R ^a   Shreve, Andrew P ^a   Dyer, R Brian ^a   Cleary, Rosemary L ^b   Ward, Michael D ^b   Bignozzi, Carlo A ^c  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

^c UNIVERSITY OF FERRARA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000121617     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9705305     Document Type: Article

References (35)

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32. At very early times following photoexcitation, the transient difference spectra contain a broad featureless absorption within which the sharper negative features due to ground-state depletion are evident. This broad absorption has not been definitively assigned, but its evolution, which could be associated with vibrational or electronic relaxation, leads to the fully evolved and stable difference spectra reported here within tens of picoseconds.
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