Thermodynamics of titanium carbide and the oxycarbide Ti2OC

High Temperature Material Processes

Volumn 1, Issue 3, 1997, Pages 393-408

  Maitre, Alexandre ^a   Cathalifaud, Philippe ^a   Lefort, Pierre ^a  

^a CNRS   (France)

Author keywords

Stability; Synthesis; Thermodynamics; Titanium carbide; Titanium oxycarbide

Indexed keywords

EID: 0000119909     PISSN: 10933611     EISSN: None     Source Type: Journal    
DOI: 10.1615/HighTempMatProc.v1.i3.90     Document Type: Article

References (19)

1. Meerson G.A. and Krein O.E., Investigation of the mechanism of the formation of titanium carbide in vacuum, J. Appl. Chem. USSR, 25 (1952) 143.
2. Pivovarov L.K., Vrzheshch E.Y., Kreimer G.S. and Zaikirov F.G., Vacant sites in the crystal lattice of TiC-TiO solid solutions, Russ. J. Inorg. Chem., 12 (1967) 917.
3. Ivanov N.A., Andreeva L.P. and Gel'd P.V., Thermal conductivities, electrical resistivities and thermal expansion of titanium carbonitrides and oxycarbides, Sov. Pow. Met. Ceram., 17 [8] (1978) 613.
4. Vicens J. and Chermant J.L., Contribution à l'étude du système titane-carbone-oxygène, Rev. Chim. Min., 9 (1972) 557.
5. Komarek K.L., Coucoulas A.and Klinger N., Reaction between refractory oxides and raphite, J. Electrochem. Soc., 110 [7] (1963) 783.
6. Berger L.M., Titanium carbide synthesis from titanium dioxide and carbon black, J. Hard Materials. 3 [1] (1992) 3.
7. Tristant P. and Lefort P., Approche cinétique de la réuction carbothermique du dioxyde de titane, J. Alloys and Compounds, 196 (1993) 137.
8. 2OC, J. Chim. Phys., 93 (1996) 2025.
9. Ouensanga A., Thermodynamics of the Ti-C-O system at 1580 K, J. Less Common Metals, 79 (1981) 237.
10. Storms E.K., The refractory carbides. New-York and London Academic Press, 1967.
11. Shimada S. and Kozeki M., Oxidation of TiC at low temperatures, J. Materials Science. 27(1992)1869.
12. Bouayad H. and Martin C., Détermination par calorimétrie isopéribolique de la chaleur massique de matériaux céramiques. Influence du remplissage du creuset, Thermique et Energétique à travers la Science et l'Industrie. Société Française Thermique, Ed. by les éditions européennes thermique et industrie, (1994) 469.
13. Barin I., Thermomechemical data of pure subtances, VCH Verlagserllscherft mbH, Weinheim, (1993), Part. II.
14. Naylor B.F., High temperature heat contents of titanium carbide and titanium nitride, J. Am. Chem. Soc., 68 (1946) 370.
15. Levinson L.S., High temperature heat contents of TiC and ZrC, J. Phvs. Chem., 42 (1965) 2891.
16. Humphrey G.L., The heats of combustion and formation of titanium nitride (TiN) and titanium carbide (TiC), J. Am. Chem. Soc., 73 (1951) 2261.
17. Heuer A.H. and Lou V.L.K., Volatility diagrams for silica silicon nitride, and silicon carbide and their application to high-temperature decomposition and oxidation, J. Am. Ceram. Soc., 73 [10] (1990) 2785.
18. Lefort P., Tetard D. and Tristant P., Formation of aluminium carbide by carbothermal reduction of alumina : role of the gaseous aluminium phase, J. Eur. Ceram. Soc., 12 (1993) 123.
19. Maitre A., Tristant P. and Lefort P., J. Alloys and Compounds, to be published.