Stepwise insertion of alkylisocyanides into the metal-alkyne bond of half-sandwich type rhodium complexes: Synthesis and structural characterization of metallacyclobutenes and metallacyclopentenes

Chemische Berichte

Volumn 129, Issue 8, 1996, Pages 903-910

  Werner, Helmut ^a   Heinemann, Anja ^a   Windmüller, Bettina ^a   Steinert, Paul ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Alkyl isocyanides; Alkyne complexes; Insertion reactions; Metallacycles; Rhodium complexes

Indexed keywords

EID: 0000100679     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290805     Document Type: Article

References (20)

1. H. Werner, P. Schwab, A. Heinemann, P. Steinert, J. Organomet. Chem. 1995,496, 207-216.
2. Y. Wakatsuki, H. Yamazaki, H. Iwasaki, J. Am. Chem. Soc. 1973,95, 5781-5783.
3. [3a] H. Werner, J. Wolf. U. Schubert, K. Ackermann, J. Organomet. Chem. 1986, 317, 327-356.
4. [3b] I. Wolf, H. Werner, Organometallics 1987, 6, 1164-1169.
5. [3c] H. Werner, M. Baum. D. Schneider. B. Windmüller, Organometallics 1994, 13, 1089-1097.
6. [4a] H Yamazaki, K. Aoki, Y. Yamamoto, Y. Wakatsuki, J. Am. Chem. Soc. 1975, 97, 3546-3548.
7. [4b] Y. Wakatsuki, S. Miya, S. Ikuta, H. Yamazaki, Chem. Suc.. Chem. Commun. 1985, 35-37.
8. [4c] Y. Wakatsuki, K. Aoki, H. Yamazaki, J. Chem. Soc., Dal ton Trans. 1986, 1193-1199.
9. [4d] Y. Wakatsuki, S. Miya, H. Yamazaki, S. Ikuta, J. Chem. Soc., Dalton Trans. 1986, 1201-1205.
10. [4e] Y. Wakatsuki, S. Miya, H. Yamazaki, J. Chem. Soc, Dalton Trans. 1986, 1207-1212.
11. W. Hirpo, M. D. Curtis, Organometallics 1994, 13, 2706-2712.
12. [6a| p Schwab, Dissertation Universität Würzburg, 1994.
13. [6b] H. Werner, J. Orcanomet. Chem. 1995. 500, 331-336.
14. [7a] M. A. Bennett, T. Yoshida, J. Am. Chem. Soc. 1978, 100, 1750-1759.
15. [7b] T. V. Harris, J. W. Rathke, E. L. Muetterties, J. Am. Chem. Soc. 1978, 100, 6966-6977.
16. [7c] J.-M. Basset, M. Green, J. A. K. Howard, F. G. A. Stone, J. Chem. Soc., Dalton Trans. 1980, 1779-1788.
17. W D. Jones, E. T. Hessell, Or-ganome"tallies 1990, 9, 718-727.
18. S. T. Belt, S. B. Duckett. D. M. Haddleton, R. N. Perutz, Organometallics 1989, A, 748-759.
19. G. W. Harris, M. O. Albers, J. C. A. Boeyens, N. J. Coville, Organometallics 1983, 2, 609-614.
20. Further details of the crystal structure investigations are available on request from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen, on quoting the depository numbers CSD-59310 (17) and -405139 (18), the names of the authors, and the journal citation.