Syntheses and structural characterization of quadruple-bonded complexes Mo2X2Tp2 (X=Cl or Br; Tp=HBpz3, pz=pyrazolyl); transformation of η2-Tp to η3-Tp

Inorganica Chimica Acta

Volumn 249, Issue 1, 1996, Pages 115-120

  Lee, Chang Tai ^a   Chen, Jhy Der ^a   Liou, Lin Shu ^b   Wang, Ju Chun ^b  

^a CHUNG YUAN CHRISTIAN UNIVERSITY   (Taiwan)

^b SOOCHOW UNIVERSITY   (Taiwan)

Author keywords

Crystal structures; Dinuclear complexes; Molybdenum complexes; Quadruple bonded complexes

Indexed keywords

BINARY ALLOYS; CRYSTAL STRUCTURE; CRYSTALS; SYNTHESIS (CHEMICAL);

CRYSTAL DATA; DINUCLEAR COMPLEX; MOLYBDENUM COMPLEX; QUADRUPLE BONDS; QUADRUPLE-BONDED COMPLEXES; SPACE GROUPS; STRUCTURAL CHARACTERIZATION; UV-VIS SPECTRA;

MOLYBDENUM COMPOUNDS;

EID: 0000094218     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(96)05018-9     Document Type: Article

References (17)

1. F. A. Cotton and R. A. Walton, Multiple Bonds between Metals Atoms, Oxford University Press, London, 2nd edn., 1993.
2. (a) J.-D. Chen and F.A. Cotton, Inorg. Chem., 30 (1990) 6;
3. (b) J.-D. Chen, F.A. Cotton and B. Hong, Inorg. Chem., 32 (1993) 2343.
4. F.L. Campbell, F.A. Cotton and G.L. Powell, Inorg. Chem., 24 (1985) 4384.
5. F.A. Cotton and G.L. Powell, Inorg. Chem., 22 (1983) 1507.
6. P.A. Agaskar, F.A. Cotton, I.F. Fraser, M.M. Ljubica, K.W. Muir and R.D. Peacock, Inorg. Chem., 25 (1986) 2511.
7. J.-D. Chen, F.A. Cotton and R.L. Falvello, J. Am. Chem. Soc., 112 (1990) 1076.
8. (a) S. Trofimenko, J. Am. Chem Soc., 88 (1966) 1842;
9. (b) 89 (1967) 3170.
10. D.M. Collins, F.A. Cotton and C.A. Murillo, Inorg. Chem., 15 (1978) 1861.
11. F.A. Cotton, B.W.S. Kolthammewr and G.N. Mott, Inorg. Chem., 20 (1981) 3890.
12. G.M. Sheldrick, SHELXTL PLUS, Release 4.1, Siemens Analytical X-ray Instruments Inc., Karlsruhe, Germany.
13. C. Mealli, C.S. Arcus, J.L. Wilkinson, T.J. Marks and I.A. Ibers, J. Am. Chem. Soc., 98 (1976) 711.
14. D.M. Baird, K.Y. Shih, J.H. Welch and R.D. Bereman, Polyhedron, 8 (1989) 2359.
15. J.-D. Chen, F.A. Cotton and E.C. DeCaino, Inorg. Chim. Acta, 176 (1990) 215.
16. F.A. Cotton, P.E. Fanwick, J.W. Fitch, H.D. Glicksman and R.A. Walton, J. Am. Chem. Soc., 101 (1979) 1752.
17. M.D. Hopkins, W.P. Schaefer, W.H. Bronikowski, V.M. Woodruff, V.M. Miskowski, R.F. Dallinger and H.B. Gray, J. Am. Chem. Soc., 109 (1987) 408.