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It is possible to expect that the scale of the conduction band tailing is considerably less than that of the valence band in anion-substituted materials. This difference in the scales of the tails makes the tail of the conduction band rather nonobservable in the absorption or in the steady state luminescence spectra. The luminescence spectra in the long-time limit coincide practically with the exciton-phonon bands at steady-state conditions. Therefore, the process of the exciton formation from separated pairs has to occur before the radiative recombination of the particles. The rate of this process depends on the nature of the electron states and we can expect that, as the consequence, the electron tailing influences the process of the luminescence kinetics
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It is possible to expect that the scale of the conduction band tailing is considerably less than that of the valence band in anion-substituted materials. This difference in the scales of the tails makes the tail of the conduction band rather nonobservable in the absorption or in the steady state luminescence spectra. The luminescence spectra in the long-time limit coincide practically with the exciton-phonon bands at steady-state conditions. Therefore, the process of the exciton formation from separated pairs has to occur before the radiative recombination of the particles. The rate of this process depends on the nature of the electron states and we can expect that, as the consequence, the electron tailing influences the process of the luminescence kinetics.
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