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For E = N, see: (a) G. van Koten, Pure Appl. Chem. 61 (1989) 1681. (b) M.H.P. Rietveld, D.M. Grove, G. van Koten, New J. Chem. 21 (1997) 751. For E = P, see: (c) C.J. Moulton, B.L. Shaw, J. Chem. Soc. Dalton Trans. (1976) 1020. (d) H. Rimml, L.M. Venanzi, J. Organomet. Chem. 259 (1983) C6. (e) S. Nemeh, C.M. Jensen, E. Binamira-Soriaga, W.C. Kaska, Organometallics 2 (1983) 1442. (f) T. Karlen, P. Dani, D.M. Grove, P. Steenwinkel, G. van Koten, Organometallics 15 (1996) 5687. (g) B. Rybtchinsky, D. Milstein, Angew. Chem. 111 (1999) 918; Angew. Chem. Int. Ed. Engl. 38 (1999) 870. For E = S, see: (h) J. Errington, W.S. McDonald, B.L. Shaw, J. Chem. Soc. Dalton Trans. (1980) 2312. (i) J. Dupont, N. Beydoun, M. Pfeffer, J. Chem. Soc. Dalton Trans. (1989) 1715.
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For E = N, see: (a) G. van Koten, Pure Appl. Chem. 61 (1989) 1681. (b) M.H.P. Rietveld, D.M. Grove, G. van Koten, New J. Chem. 21 (1997) 751. For E = P, see: (c) C.J. Moulton, B.L. Shaw, J. Chem. Soc. Dalton Trans. (1976) 1020. (d) H. Rimml, L.M. Venanzi, J. Organomet. Chem. 259 (1983) C6. (e) S. Nemeh, C.M. Jensen, E. Binamira-Soriaga, W.C. Kaska, Organometallics 2 (1983) 1442. (f) T. Karlen, P. Dani, D.M. Grove, P. Steenwinkel, G. van Koten, Organometallics 15 (1996) 5687. (g) B. Rybtchinsky, D. Milstein, Angew. Chem. 111 (1999) 918; Angew. Chem. Int. Ed. Engl. 38 (1999) 870. For E = S, see: (h) J. Errington, W.S. McDonald, B.L. Shaw, J. Chem. Soc. Dalton Trans. (1980) 2312. (i) J. Dupont, N. Beydoun, M. Pfeffer, J. Chem. Soc. Dalton Trans. (1989) 1715.
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Notably, mesylation is fast and requires low temperatures to retain the optical purity, since these conditions successfully prevented nucleophilic substitution of the mesylate by residual chloride ions and subsequent racemization, see e.g. (a) W.T.S. Huck, F.C.J.M. van Veggel, D.N. Reinhoudt, J. Mater. Chem. 7 (1997) 1213. (b) P.J. Davies, D.M. Grove, G. van Koten, Organometallics 16 (1997) 800.
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0347800838
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note
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3)N], see Ref. [30].
-
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76
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0347800839
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note
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Due to the puckered metallacycles, the R,S- and the S,R-isomers may be distinguished, since they are enantiotopic to each other. The term meso is therefore misleading and has been avoided for the description of the configuration of square-planar metal complexes (but not of ligand precursors). Only when the wagging of the metallacycles is fast, the meso-isomer is observed as an averaged structure. (Equation Presented)
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-
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77
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For pincer complexes on heterogeneous supports, see: (a) C. Pathmamanoharan, P. Wijkens, D.M. Grove, A.P. Philipse, Langmuir 12 (1996) 4372. For recent achievements in dendrimer chemistry, see: (b) G. van Koten, J.T.B.H. Jastrzebski, J. Mol Catal. A: Chem. 146 (1999) 317.
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For pincer complexes on heterogeneous supports, see: (a) C. Pathmamanoharan, P. Wijkens, D.M. Grove, A.P. Philipse, Langmuir 12 (1996) 4372. For recent achievements in dendrimer chemistry, see: (b) G. van Koten, J.T.B.H. Jastrzebski, J. Mol Catal. A: Chem. 146 (1999) 317.
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(c) N.J. Hovestad, E.B. Eggeling, H.J. Heidbüchel, J.T.B.H. Jastrzebski, U. Kragl, W. Keim, D. Vogt, G. van Koten, Angew. Chem. 111 (1999) 1763; Angew. Chem. Int. Ed. Engl. 38 (1999) 1655.
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(c) N.J. Hovestad, E.B. Eggeling, H.J. Heidbüchel, J.T.B.H. Jastrzebski, U. Kragl, W. Keim, D. Vogt, G. van Koten, Angew. Chem. 111 (1999) 1763; Angew. Chem. Int. Ed. Engl. 38 (1999) 1655.
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0034646883
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(a) M. Albrecht, M. Lutz, A.L. Spek, G. van Koten, Nature 406 (2000) 970.
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0029961915
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0002233116
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This reaction requires an organolithium reagent and does not proceed well with the corresponding organomagnesium reagents, see: (a) M.J. Jorgenson, Org. React. 18 (1970) 1. (b) G.M. Rubottom, C.-W. Kim, J. Org. Chem. 48 (1983) 1550.
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0001642794
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This reaction requires an organolithium reagent and does not proceed well with the corresponding organomagnesium reagents, see: (a) M.J. Jorgenson, Org. React. 18 (1970) 1. (b) G.M. Rubottom, C.-W. Kim, J. Org. Chem. 48 (1983) 1550.
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90
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0347800834
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The term ortho,ortho denotes the position ortho to both nitrogen-containing substituents of the arene, whereas ortho,ortho′ is referred to as the position ortho to two different substituents, i.e. ortho to the oxo-substituent and to one nitrogen-containing substituent
-
The term ortho,ortho denotes the position ortho to both nitrogen-containing substituents of the arene, whereas ortho,ortho′ is referred to as the position ortho to two different substituents, i.e. ortho to the oxo-substituent and to one nitrogen-containing substituent
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98
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0001145328
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G. van Koten, J.T.B.H. Jastrzebski, J.G. Noltes, A.L. Spek, J.C. Schoone, J. Organomet. Chem. 148 (1977) 233.
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0001287342
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Van Koten, G.8
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100
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0346540559
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note
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2O quenches revealed 60-80% product resulting from retro-[1,2]-Brook rearrangement, dependent on whether n-BuLi or t-BuLi was used.
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note
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Notably, reduction of the brominated ketone 12 (available from oxidation of rac/meso-11 by pyridinium chlorochromate) afforded the diol R,R-11 in higher optical purity (typically 94-97% of the desired stereoisomer) than reduction of the non-brominated analog R,R-6a (typically 90%). Presumably, the steric demand of the bromide substituent positively influences the crucial intermediates during the CBS reduction.
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