Kinetics and Mechanism of the Reactions of Sulfito Complexes in Aqueous Solution. 3. Formation, Acid-Catalyzed Decomposition, and Intramolecular Isomerization of Oxygen-Bonded (αβS)-(Sulfito)(tetraethylenepentamine)cobalt(III) Ion and the Hydrolysis of Its Sulfur-Bonded Analogue

Inorganic Chemistry

Volumn 20, Issue 10, 1981, Pages 3160-3166

  Dash, A C ^a   El Awady, A A ^a   Harris, G M ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000066463     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic50224a007     Document Type: Article

References (20)

1. Previous paper in this series: El-Awady, A.A.; Harris, G.M. Inorg. Chem. 1981, 20, 1660.
2. On leave from the Department of Chemistry, Western Illinois Universtiy, Macomb, 111. 61455.
3. van Eldik, R.; Harris, G.M. Inorg. Chem. 1980, 19, 880. 5) Dasgupta, T.P.; Harris, G.M., in preparation.
4. El-Awady, A.A.; Harris, G.M., in preparation. 7) El-Awady, A.A.; Harris, G.M. Inorg. Chem., in press.
5. House, D.A.; Garner, C.S. Inorg. Chem. 1966, 5, 2097.
6. House, D.A.; Garner, C.S. Inorg. Chem. 1967, 6, 272.
7. These complexes, erroneously characterized by House and Garner as a isomers, are in fact β5 isomers: Snow, M.R.; Buckingham, D.A.; Marzilli, P.A.; Sargeson, A.M. Chem. Commun. 1969, 891. Snow, M.R. J. Chem. Soc., Dalton Trans. 1972, 1627.
8. Galbraith Laboratories, Inc., Knoxville, Tenn. 37921.
9. Scott, K.L. J. Chem. Soc., Dalton Trans. 1974, 1486.
10. Elder, R.C.; Heeg, M.J.; Payne, M.D.; Trkula, M.; Dcutsch, E. Inorg. Chem. 1978, 17, 431.
11. Baldwin, M.E. J. Chem. Soc. 1961, 3123
12. Hughes, R.G.; Endicott, J.F.; Hoffman, H.Z.; House, D.A. J. Chem. Educ. 1969, 46, 440.
13. El-Awady, A.A. J. Chem. Soc., Dalton Trans. 1972, 1463; 1974,1265.
14. Ni, T.; Garner, C.S. Inorg. Chem. 1967, 6, 1071. 20) Simultaneous S02 uptake by (αβS)-[Co(tetren)OH2]3+ (k0) and (αβS)-[Co(tetren)OH]2+ (kt) will have kf = [(k0/K3)[H+] + k1||K3/(K3 + [H+])fi[S]T.
15. Taube, H.; Posey, F.A. J. Am. Chem. Soc. 1953, 75, 1463.
16. Farrell, S.M.; Murray, R.S. J. Chem. Soc., Dalton Trans. 1977, 322.
17. Farrell, S.M.; Murray, R.S. J. Chem. Soc., Dalton Trans. 1977, 322.
18. Basolo, F.; Hammaker, G.S. Inorg. Chem. 1962, 1,1.
19. Mares, M.; Palmer, D.A.; Kelm, H. Inorg. Chim. Acta 1978, 27, 153.
20. Jackson, W.G.; Lawrance, G.A.; Lay, P.A.; Sargeson, A.M. Inorg. Chem. 1980, 19, 904.