Structural and 99Tc NMR Investigations of Complexes with fac-[Tc(CO)3]+ Moieties and Macrocyclic Thioethers of Various Ring Sizes: Synthesis and X-ray Structure of the Complexes fac-[Tc(9-ane-S3)(CO)3]Br, fac-[Tc2(tosylate)2(18-ane-S6)(CO) 6], and

Inorganic Chemistry

Volumn 37, Issue 14, 1998, Pages 3509-3516

  Schibli, Roger ^a   Alberto, Roger ^b   Abram, Ulrich ^c   Abram, Sonja ^c   Egli, André ^b   Schubiger, P August ^b   Kaden, Thomas A ^d  

^a UNIVERSITY OF MISSOURI   (United States)

^b PAUL SCHERRER INSTITUTE   (Switzerland)

^c DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

^d UNIVERSITY OF BASEL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000060813     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980112f     Document Type: Article

References (35)

1. Blake, A. J.; Schröder, M. Adv. Inorg. Chem. 1990, 35, 1 and references therein.
2. (a) White, D. J.; Küppers, H.-J.; Edwards, A. J.; Watkin, D. J.; Cooper, S. R. Inorg. Chem. 1992, 31, 5351.
3. (b) White, D. J.; Küppers, H.-J.; Matondo, S. O. C.; Jones, W. B.; Mountford, P.; Edwards, A. J.; Watkin, D. J.; Cooper, S. R. In Technetium and Rhenium in Chemistry and Nuclear Medicine; Nicolini, M., Bandoli, G., Mazzi, U., Eds.; SGE: Padua, Italy, 1995; Vol. 4, p 469.
4. (c) Pietzsch, H.-J.; Spies, H.; Leibnitz, P.; Reck, G.; Berger, J.; Jacobi, R. Polyhedron 1992, 11, 1623.
5. (d) Pietzsch, H.-J.; Spies, H.; Leibnitz, P.; Reck, G.; Berger, J.; Jacobi, R. Polyhedron 1993, 72, 187.
6. (e) Pietzsch, H.-J.; Spies, H.; Leibnitz, P.; Reck, G. Polyhedron 1995, 14, 1849.
7. Knight Castro, H. H.; Hissink, C. E.; Teuben, J. H.; Vaalburg, W. Recl. Trav. Chim. Pay-Bas 1992, 111, 105. Pietzsch, H.-J.; Spies, H.; Leibnitz, P.; Reck, G. Polyhedron 1993, 72, 2995.
8. Knight Castro, H. H.; Hissink, C. E.; Teuben, J. H.; Vaalburg, W. Recl. Trav. Chim. Pay-Bas 1992, 111, 105. Pietzsch, H.-J.; Spies, H.; Leibnitz, P.; Reck, G. Polyhedron 1993, 72, 2995.
9. Lee, M. T. B.; Seliskar, C. J.; Heineman, W. R.; McGoron, A. J. Appl. Radiat. Iost. 1996, 47, 207. Lorenz, B.; Findeisen, M.; Oik, B.; Schmidt, K. Z. Anorg. Allg. Chem. 1988, 566, 160. Abrams, M. J.; Davison, A.; Jones, A. G.; Costello, C. E.; Pang, H. Inorg. Chem. 1983, 22, 2798. Vanderheyden, J.-L.; Ketring, A. R.; Libson, K.; Heeg, M. J.; Roecker. L.; Motz. P.; Whittle, R.; Elder, R. C.; Deutsch, E. Inorg. Chem. 1984, 23, 3184.
10. Lee, M. T. B.; Seliskar, C. J.; Heineman, W. R.; McGoron, A. J. Appl. Radiat. Iost. 1996, 47, 207. Lorenz, B.; Findeisen, M.; Oik, B.; Schmidt, K. Z. Anorg. Allg. Chem. 1988, 566, 160. Abrams, M. J.; Davison, A.; Jones, A. G.; Costello, C. E.; Pang, H. Inorg. Chem. 1983, 22, 2798. Vanderheyden, J.-L.; Ketring, A. R.; Libson, K.; Heeg, M. J.; Roecker. L.; Motz. P.; Whittle, R.; Elder, R. C.; Deutsch, E. Inorg. Chem. 1984, 23, 3184.
11. Lee, M. T. B.; Seliskar, C. J.; Heineman, W. R.; McGoron, A. J. Appl. Radiat. Iost. 1996, 47, 207. Lorenz, B.; Findeisen, M.; Oik, B.; Schmidt, K. Z. Anorg. Allg. Chem. 1988, 566, 160. Abrams, M. J.; Davison, A.; Jones, A. G.; Costello, C. E.; Pang, H. Inorg. Chem. 1983, 22, 2798. Vanderheyden, J.-L.; Ketring, A. R.; Libson, K.; Heeg, M. J.; Roecker. L.; Motz. P.; Whittle, R.; Elder, R. C.; Deutsch, E. Inorg. Chem. 1984, 23, 3184.
12. Lee, M. T. B.; Seliskar, C. J.; Heineman, W. R.; McGoron, A. J. Appl. Radiat. Iost. 1996, 47, 207. Lorenz, B.; Findeisen, M.; Oik, B.; Schmidt, K. Z. Anorg. Allg. Chem. 1988, 566, 160. Abrams, M. J.; Davison, A.; Jones, A. G.; Costello, C. E.; Pang, H. Inorg. Chem. 1983, 22, 2798. Vanderheyden, J.-L.; Ketring, A. R.; Libson, K.; Heeg, M. J.; Roecker. L.; Motz. P.; Whittle, R.; Elder, R. C.; Deutsch, E. Inorg. Chem. 1984, 23, 3184.
13. (a) Alberto, R.; Schibli, R.; Egli, A.; Schubiger, P. A.; Herrmann, W. A.; Artus, G.; Abram, U.; Kaden, T. A. J. Organomet, Chem. 1995, 493, 119.
14. (b) Alberto, R.; Schibli, R.; Schubiger, P. A.; Abram, U.; Hübener, R.; Berke, H.; Kaden, T. A. Chem. Commun. 1996, 1291.
15. (a) Alberto, R.; Schibli, R.; Schubiger, P. A.; Abram, U.; Kaden, T. A. Polyhedron 1996, 15, 1079.
16. (b) Abram, U.; Abram, S.; Alberto, R.; Schibli, R. Inorg. Chim. Acta 1996, 248, 19.
17. (c) Abram, U.; Abram, S.; Schibli, R.; Alberto, R.; Dilworth, J. R. Polyhedron, in press,
18. (d) Alberto, R.; Schibli, R.; Abram, U.; Kaden, T. A.; Schubiger, P. A. J. Chem. Soc., Dalton Trans., submitted for publication.
19. (e) Alberto, R.; Schibli, R.; Abram, U.; Angst, D.; Schubiger, P. A. Transition Met. Chem., in press,
20. (f) Alberto, R.; Schibli, R.; Abram, U.; Egli, A.; Knapp, F. F.; Schubiger, P. A. Radiochim. Acta, in press.
21. Alberto, R.; Nef, W.; Smith, A.; Kaden, T. A.; Neuburger, M.; Zehnder, M.; Frey, A.; Abram, U.; Schubiger, P. A. Inorg. Chem. 1996, 35, 3420.
22. Sheldrick, G. M. SHELXS-86: A Program for Crystal Structure Determination; University of Göttingen: Göttingen, Germany, 1986.
23. Sheldrick, G. M. SHELXL-93: A Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1993.
24. Pomp, C.; Drücke, S.; Küppers, H.-J.; Wieghardt, K. Z. Naturforsch. 1988, 43b, 299.
25. O'Connell, L.; Pearstein, R. M.; Davison, A. Inorg. Chim. Acta 1989, 161, 39.
26. Findeisen, M.: Kaden, L.; Lorenz, B.; Wahren, M. Inorg. Chim. Acta 1988, 142, 3.
27. Bell, M. N.; Blake, A. J.; Schröder, M.; Stephenson, T. A. J. Chem. Soc., Chem. Commun. 1986, 471.
28. DeSimone, R. E.; Glick, M. D. J. Am. Chem. Soc. 1976, 98, 762.
29. Wolf, R. E. J.; Hartman, J. R.; Storey, J. M.; Foxman, B. M.; Cooper S. R. J. Am. Chem. Soc. 1987, 109, 4328.
30. Hartman, J. R.; Wolf, R. E. J.; Foxman, B. M.; Cooper, S. R. J. Am. Chem. Soc. 1983, 105, 131.
31. Glass, R. S.; Wilson, G. S.; Setzer, W. N. J. Am. Chem. Soc. 1980, 102, 5068.
32. Dale, J. Isr. J. Chem. 1980, 20, 3.
33. -) represents a gauche (±60°) conformation with clockwise (counterclockwise) torsion from the eclipsed angle; the designation a represents an antiperiplanar (180°) and a* an anticlinal (±120°) placement.
34. Riley, D. P.; Oliver, J. D. Inorg. Chem. 1983, 22, 3361.
35. Zolnai, L. ZORTEP: A Program for the Ellipsoid Representation of Structures; University of Heidelberg: Heidelberg, Germany, 1997.