Formation of the intermediate, aquohydroxobis (ethylenediamine)cobalt(III) complex, in the preparation of cis-bromoamminebis (ethylenediamine)cobalt(III) bromide by the reaction of bis[bis(ethylenediamine)cobalt(III)-μ-dihydroxo]diaquocobalt(II) sulfate with ammonium bromide in water

Journal of Coordination Chemistry

Volumn 46, Issue 2, 1998, Pages 159-164

  Asakura, Kouichi ^a,b   Inoue, Kazuya ^b   Osanai, Shuichi ^b   Kondepudi, Dilip K ^a  

^a WAKE FOREST UNIVERSITY   (United States)

^b KEIO UNIVERSITY   (Japan)

Author keywords

Ammonium bromide; Cobalt; Ethylenediamine; Intermediate; Reaction mechanisms

Indexed keywords

EID: 0000059538     PISSN: 00958972     EISSN: None     Source Type: Journal    
DOI: 10.1080/00958979808053727     Document Type: Article

References (17)

1. A. Werner and W.E. Boes, Ann., 386, 178 (1912).
2. A. Werner, Ann., 386, 176 (1912).
3. A. Werner, Ann., 386, 179 (1912).
4. M.L. Tobe and D.F. Martin, Inorg. Synth., 8, 198 (1966).
5. A. Werner, Ber., 40, 1887 (1911).
6. G.B. Kauffman and E.V. Lindley Jr., J. Chem. Educ., 51, 424 (1974).
7. I. Bernal, J Cetrullo and W.G. Jackson, Inorg. Chem., 32, 4098 (1993).
8. H. Nakagawa, S. Ohba, K. Asakura, T. Miura, A. Tanaka and S. Osanai, Acta Crytallograph., C53, 216 (1997).
9. K. Asakura, K. Kobayashi, Y. Mizusawa, T. Ozawa, S. Osanai and S. Yoshikawa, Physica D, 84, 72 (1995).
10. K. Asakura and S. Osanai, Nippon Kessho Gakkaishi, 38, 229 (1996).
11. K. Asakura, K. Kobayashi, Y. Mizusawa, T. Ozawa, T. Miura, A. Tanaka, Y. Kushibe and S. Osanai, Recent Research Developments in Pure & Applied Chemistry, 1, 123 (1997).
12. H. Kobayashi, K. Ohki, I. Tsujikawa, K. Osaki and N. Uryu, Bull. Chem. Soc. Jpn., 49, 1210 (1976).
13. R.D. Cannon and J.E. Earley, J. Am. Chem. Soc., 88, 1872 (1965).
14. 2 are identical, and the results are interpreted that both isomers readily rearrange to an equilibrium mixture: F. Basolo, J. Am. Chem. Soc., 72, 4393 (1950).
15. -1: (a) R.S. Nyloholm and M.L. Tobe, J. Chem. Soc., 1956, 1707. (b) J.F. Remar, and D.E. Pennington and A Haim. Inorg. Chem., 4, 1832 (1965)).
16. -1: (a) R.S. Nyloholm and M.L. Tobe, J. Chem. Soc., 1956, 1707. (b) J.F. Remar, and D.E. Pennington and A Haim. Inorg. Chem., 4, 1832 (1965)).
17. 2(%): C, 11.02; H, 4.39; N, 16.07; Br, 54.99. Found: C, 11.26; H, 4.23, N, 15.93, Br, 54.28.