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Volumn 16, Issue 35, 1975, Pages 3065-3068

Syntheses of macrocyclic terpenoids by intramolecular cyclization I. (±)-cembrene-a, a termite trail pheromone, and (±)-nephthenol

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EID: 0000052065     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)75075-1     Document Type: Article
Times cited : (73)

References (20)
  • 16
    • 37049129746 scopus 로고
    • As far as we are aware, this is the first example of intramolecular reaction of the anion of allyl thioether. Intermolecular reaction of such an anion with epoxide has been used for the synthesis of Cecropia juvenile hormone, Chem. Commun.
    • (1972) J. Chem. Soc. , pp. 1311
    • Kondo1    Negishi2    Matsui3    Tunetomo4    Masamune5
  • 18
    • 84918296124 scopus 로고    scopus 로고
    • The alcohol 6 shows no indication (tlc, nmr) for the presence of its epimer. The reaction mixture indicates no sign of the starting material 5 but the presence of more polar substances which have not been investigated further.
  • 19
    • 84918296123 scopus 로고    scopus 로고
    • 3-methyl is attributed to the anisotropic effect of phenyl group closely situated.
  • 20
    • 84918296122 scopus 로고    scopus 로고
    • The spectra of natural nephthenol kindly supplied by Professor Schmitz indicates that it still contains a small amount of ketonic material. It is clear, however, that the synthetic nephthenol is identical with the major constituent of the substance from the natural source.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.