Alkoxo Bound Monooxo- and Dioxovanadium(V) Complexes: Synthesis, Characterization, X-ray Crystal Structures, and Solution Reactivity Studies

Inorganic Chemistry

Volumn 35, Issue 19, 1996, Pages 5674-5683

  Asgedom, Gebray ^a   Sreedhara, Alavattam ^a   Kivikoski, Jussi ^b   Valkonen, Jussi ^b   Kolehmainen, Erkki ^b   Rao, Chebrolu P ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000047653     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960061r     Document Type: Article

References (45)

1. Robson, R. L.; Eady, R. R.; Richardson, T. H.; Miller, R. W.; Hawkins, M.; Postgate, J. R. Nature (London) 1986, 322, 388.
2. (a) Vilter, H. Phytochemistry 1984, 23, 1387.
3. (b) Wever, R.; de Boer, E.; Plat, H.; Krenn, B. E. FEBS Lett. 1987, 216, 1.
4. Kneifel, H.; Bayer, E. Angew. Chem., Int. Ed. Engl. 1973, 12, 508.
5. Smith, M. J.; Kim, D.; Horenstein, B.; Nakanishi, K.; Kustin, K. Acc. Chem. Res. 1991, 24, 117.
6. (a) Messerschmidt, A.; Wever, R. J. Inorg. Biochem, 1995, 59, 580.
7. (b) Messerschmidt, A.; Wever, R. Proc: Natl. Acad. Sci. U.S.A. 1996, 93, 392.
8. (a) Clague, M. J.; Keder, N. L.; Butler, A. Inorg. Chem. 1993, 32, 4754.
9. (b) Clague, M. J.; Butler, A. J. Am. Chem. Soc. 1995, 117, 3475.
10. Butler, A.; Danzitz, M. J. J. Am. Chem. Soc. 1987, 109, 1864.
11. Arber, J. M.; de Boer, E.; Garner, C. D.; Hasnain, S. S.; Wever, R. Biochemistry 1989, 28, 7968.
12. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 4th Ed.; 1980.
13. (a) Chakravarty, J.; Dutta, S.; Chandra, S. K.; Basu, P.; Chakravorty, A. Inorg. Chem. 1993, 32, 4249.
14. (b) Mondal, S.; Dutta, S.; Chakravorty, A. J. Chem. Soc., Dalton Trans. 1995, 1115.
15. Chakravarty, J.; Dutta, S.; Dey, A.; Chakravorty, A. J. Chem. Soc., Dalton Trans. 1994, 557.
16. Bonadies, J. A.; Carrano, C. J. J. Am. Chem. Soc. 1986, 108, 4088.
17. (a) Syamal, A.; Kale, K. S. Inorg. Chem. 1979, 18, 992.
18. (b) Carrano, C. J.; Nunn, C. M.; Quan, R.; Bonadies, J. A.; Pecoraro, V. L. Inorg. Chem. 1990, 29, 944.
19. Asgedom, G.; Sreedhara, A.; Kivikoski, J.; Valkonen, J.; Rao, C. P. J. Chem. Soc., Dalton Trans. 1995, 2459.
20. (a) Asgedom, G.; Sreedhara, A.; Rao, C. P. Polyhedron 1995, 14, 1873.
21. (b) Asgedom, G.; Sreedhara, A.; Kolehmainen, E.; Rao, C. P. Polyhedron, in press,
22. Sreedhara, A.; Susa, N.; Patwardhan, A.; Rao, C. P. Biochem. Biophys. Res. Commun. 1996, 224, 115.
23. Asgedom, G.; Sreedhara, A.; Kivikoski, J.; Kolehmainen, E.; Rao, C. P. J. Chem. Soc., Dalton Trans. 1996, 93.
24. Giacomelli, A.; Floriani, C.; de Souza Duarte, A. O.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1982, 21, 3310.
25. Sheldrick, G. M. SHELXS86, Program for the Solution of Crystal Structures; University of Gottingen: Gottingen, Germany, 1986.
26. Watkin, D. J.; Carruthers, J. R.; Betteridge, P. W. CRYSTALS, Chemical Crystallography Laboratory; University of Oxford: Oxford, U.K., 1990.
27. Johnson, C. K. ORTEP; Report ORNL-5138; Oak Ridge National Laboratory: Oak Ridge, TN, 1976.
28. Khoo, L. E.; Charland, J.-P.; Gabe, E. J.; Smith, F. E. Inorg. Chim. Acta 1987, 128, 130.
29. Muetterties, E. L.; Guggenberger, L. J. J. Am. Chem. Soc. 1974, 96, 1748.
30. Carrano, C. J.; Mohan, M.; Holmes, S. M.; de la Rosa, R.; Butler, A.; Charnock, J. M.; Garner, C. D. Inorg. Chem. 1994, 33, 646.
31. Cornman, C. R.; Colpas, G. J.; Hoeshele, J. D.; Kampf, J.; Pecoraro, V. L. J. Am. Chem. Soc. 1992, 114, 9925.
32. Bergel, F.; Bray, R. C.; Harrap, K. R. Nature (London) 1958, 181, 1654.
33. Root, C. A.; Hoeschele, J. D.; Cornman, C. R.; Kampf, J. W.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3855.
34. Hillerns, F.; Olbrich, F.; Behrens, U.; Rehder, D. Angew. Chem., Int. Ed. Engl. 1992, 31, 447.
35. Caughlan, C. N.; Smith, H. M.; Watenpaugh, K. Inorg. Chem. 1966, 12, 2131.
36. Cotton, F. A.; Lewis, G. E.; Mott, G. N. Inorg. Chem. 1983, 22, 378.
37. Priebsch, W.; Rehder, D. Inorg. Chem. 1990, 29, 3013.
38. Crans, D. C.; Felty, R. A.; Miller, M. M. J. Am. Chem. Soc. 1991, 113, 265.
39. Musiani, M. M.; Milani, F.; Graziani, R.; Vidali, M.; Casellato, U.; Vigato, P. A. Inorg. Chim. Acta 1982, 61, 115.
40. Li, X.; Lah, M. S.; Pecoraro, V. L. Inorg. Chem. 1988, 27, 4657.
41. Hambley, T. W.; Judd, R. J.; Lay, P. A. Inorg. Chem. 1992, 31, 343.
42. Colpas, G. J.; Hamstra, B. J.; Kampf, J. W.; Pecoraro, V. L. Inorg. Chem. 1994, 33, 4669.
43. Asgedom, G.; Sreedhara, A.; Kivikoski, J.; Rao, C. P. Polyhedron, in press.
44. Holmes, S.; Carrano, C. J. Inorg. Chem. 1990, 30, 1231.
45. -3 near S was observed in the final Fourier difference map. Selected bond lengths (A) and angles (deg) are as follows: V-O(1) = 1.87(1); V-O-(2A) = 1.911(9): V-O(2B) = 2.27(1); V-O(3) = 1.784(9); V-O-(6) = 1.60(1); V-N(1) = 2.14(1); O(1)-V-O(2) = 152.7(5); O(1)-V-O(3) = 96.3(4); O(1)-V-O(6) = 101.9(6); O(1)-V-N(1) = 85.4(4); O(2)-V-O(6) = 170.6(5); N(1)-V-O(3) = 169.0(4); O(6)-V-N(1) = 89.7(5); O(3)-V-O(6) = 100.8(5).