Cleavable double-chain surfactants with one cationic and one anionic head group that form vesicles

Langmuir

Volumn 12, Issue 18, 1996, Pages 4314-4316

  Jaeger, David A ^a   Li, Bei ^a   Clark Jr , Theotis ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000045845     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la960012r     Document Type: Article

References (39)

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6. For examples, see (a) Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448. (b) Song, L. D.; Rosen, M. J. Langmuir 1996, 12, 1149. (c) Zana, R.; Talmon, Y. Nature 1993, 362, 228. (d) Menger, F. M.; Littau, C. A. J. Am. Chem. Soc. 1993, 115, 10083. (e) Devínsky, F.; Lacko, I.; Imam, T. J. Colloid Interface Sci. 1991, 143, 336. (f) Abid, S. K.; Hamid, S. M.; Sherrington, D. C. J. Colloid Interface Sci. 1987, 120, 245. (g) Imam, T.; Devínsky, F.; Lacko, I.; Mlynarcik, D.; Krasnec, L. Pharmazie 1983, 38, 308, and references therein.
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10. For examples, see (a) Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448. (b) Song, L. D.; Rosen, M. J. Langmuir 1996, 12, 1149. (c) Zana, R.; Talmon, Y. Nature 1993, 362, 228. (d) Menger, F. M.; Littau, C. A. J. Am. Chem. Soc. 1993, 115, 10083. (e) Devínsky, F.; Lacko, I.; Imam, T. J. Colloid Interface Sci. 1991, 143, 336. (f) Abid, S. K.; Hamid, S. M.; Sherrington, D. C. J. Colloid Interface Sci. 1987, 120, 245. (g) Imam, T.; Devínsky, F.; Lacko, I.; Mlynarcik, D.; Krasnec, L. Pharmazie 1983, 38, 308, and references therein.
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15. Surfactants 1, with an alkyl chain located at or near each head group, are distinct from double-chain zwitterionic surfactants such as phosphocholines. In the latter, the cationic and anionic units are part of a relatively compact zwitterionic head group. Thus phosphocholines are appropriately classified as double-chain, single (zwitterionic)-head-group surfactants.
16. Vesicles can also be prepared from mixtures of single-chain cationic and anionic surfactants. For examples, see (a) Hirano, K.; Fukuda, H.; Regen, S. L. Langmuir 1991, 7, 1045. (b) Kaler, E. W.; Murthy, A. K.; Rodriguez, B. E.; Zasadzinski, J. A. N. Science 1989, 245, 1371.
17. Vesicles can also be prepared from mixtures of single-chain cationic and anionic surfactants. For examples, see (a) Hirano, K.; Fukuda, H.; Regen, S. L. Langmuir 1991, 7, 1045. (b) Kaler, E. W.; Murthy, A. K.; Rodriguez, B. E.; Zasadzinski, J. A. N. Science 1989, 245, 1371.
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21. 13C NMR spectra consistent with their structures and satisfactory carbon and hydrogen combustion analyses.
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29. 2O at 30°C for 8 h. Then the mixture was shaken for ca. 2 s, and an aliquot was transferred to fill the well of a 14-mm (i.d.) × 2.5-mm (width) rubber washer cemented onto a glass slide. The well was sealed with a cover slip, and observation of the sample at 23°C was begun at 200× magnification with a Nikon Diaphot-TMD inverted microscope connected, in order, to a Cohu 4915-2110 CCD solid state camera, Panasonic WJ-180 time-date generator, Sanyo GVR-S5955 SVHS videocassette recorder, Sony UP-2200 color video printer, and Sony PVM-1343MD color video monitor. The photographs of Figure 1 were obtained within 1 h of adding the sample to the well.
30. 2H. The photograph of Figure 2 was obtained at 100× magnification.
31. The appearance of 2 relative to the internal standard was monitored.
32. +] experienced by vesicular 1 will be less than that experienced by unaggregated 1 in the bulk aqueous phase, imparting a lesser reactivity to the former. For a pertinent discussion of related systems, see Jaeger, D. A.; Mohebalian, J.; Rose, P. L. Langmuir 1990, 6, 547.
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