Direct synthesis of a bis(pyrazolyl)boratocopper(I) complex: Synthesis and characterization of [H2B(3,5-(CF3)2]Pz2]Cu(PPh3)2 displaying an unusual coordination mode for a poly(pyrazolyl)borate ligand

Inorganic Chemistry

Volumn 39, Issue 10, 2000, Pages 2246-2248

  Rasika Dias, H V ^a   Lu, Hui Ling ^a  

^a UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; COPPER COMPLEX;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTALLOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS;

EID: 0000035214     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991385t     Document Type: Article

References (10)

1. Trofimenko, S. Chem. Rev. 1993, 93, 943-980. Trofimenko, S. Scorpionates: The Coordination Chemistry of Poly(pyrazolyl)borate Ligands; Imperial College Press: London, 1999.
2. Trofimenko, S. Chem. Rev. 1993, 93, 943-980. Trofimenko, S. Scorpionates: The Coordination Chemistry of Poly(pyrazolyl)borate Ligands; Imperial College Press: London, 1999.
3. Kitajima, N.; Tolman, W. B. Prog. Inorg. Chem. 1995, 43, 419-531.
4. Shaver, A. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: New York, 1987; Vol. 2, p 245.
5. Niedenzu, K.; Trofimenko, S. Top. Curr. Chem. 1986, 131, 1-37.
6. Parkin, G. Adv. Inorg. Chem. 1995, 42, 291-393.
7. Silver and thallium derivatives have also been used as ligand transfer agents. However, they are also obtained using alkali-metal poly(pyrazolyl)borates and silver or thallium salts.
8. Marks, T. J.; Kolb, J. R. Chem. Rev. 1977, 77, 263-293.
9. James, B. D.; Wallbridge, M. G. H. Prog. Inorg. Chem. 1970, 11, 99-231.
10. Dias, H. V. R.; Gorden, J. D. Inorg. Chem. 1996, 35, 318-324.