Iconography of Icosahedra. Calculations of Metallic Energies and Relative Stabilities of Stereoisomers of Binary Icosahedral Clusters

Inorganic Chemistry

Volumn 37, Issue 10, 1998, Pages 2482-2495

  Teo, Boon K ^a   Strizhev, Alex ^a   Elber, Ron ^a   Zhang, Hong ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000033936     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980006d     Document Type: Article

References (84)

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82. Similar reversals of surface/core metal compositions are also experimentally documented from surface-science studies of bimetallic systems (denoted as the chemisorption-induced aggregation model) if an adsorbate gas binds much more strongly to the metal component with the higher cohesive energy (e.g., Pt-Au alloys in ultrahigh vacuum vs in the presence of CO). See, for example: (a) Sinfelt, J. H. Acc. Chem. Res. 1987, 20, 134. (b) Sachtler, W. M. H.; van Santen, R. A. Adv. Catal. 1997, 26, 69. Sinfelt, J. H. Prog. Solid State Chem. 1975, 10, 55.
83. Similar reversals of surface/core metal compositions are also experimentally documented from surface-science studies of bimetallic systems (denoted as the chemisorption-induced aggregation model) if an adsorbate gas binds much more strongly to the metal component with the higher cohesive energy (e.g., Pt-Au alloys in ultrahigh vacuum vs in the presence of CO). See, for example: (a) Sinfelt, J. H. Acc. Chem. Res. 1987, 20, 134. (b) Sachtler, W. M. H.; van Santen, R. A. Adv. Catal. 1997, 26, 69. (c) Sinfelt, J. H. Prog. Solid State Chem. 1975, 10, 55.
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