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Volumn 61, Issue 25, 1996, Pages 8878-8884

Stereochemistry of the Vinylic SRN1 Reaction of Triarylvinyl Halides. the Structure of the Intermediate α-Arylvinyl Radical

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EID: 0000032586     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo961007v     Document Type: Article
Times cited : (20)

References (74)
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    • ACS Monograph 178; American Chemical Society: Washington, DC
    • RN1 Mechanism; ACS Monograph 178; American Chemical Society: Washington, DC, 1983.
    • (1983) RN1 Mechanism
    • Rossi, R.A.1    De Rossi, R.H.2
  • 9
    • 0000863954 scopus 로고
    • See: (a) Miller, S. I.; Lee, W. G. J. Am. Chem. Soc. 1959, 81, 6313.
    • (1959) J. Am. Chem. Soc. , vol.81 , pp. 6313
    • See1
  • 12
    • 33845373650 scopus 로고
    • Here, an E → Z isomerization barrier of 26.6 kcal/mol for 1-propenyl anions is calculated.
    • Froelicher, S. W.; Freiser, B. S.; Squires, R. R. Ibid. 1986,108, 2853. Here, an E → Z isomerization barrier of 26.6 kcal/mol for 1-propenyl anions is calculated.
    • (1986) Ibid. , vol.108 , pp. 2853
    • Froelicher, S.W.1    Freiser, B.S.2    Squires, R.R.3
  • 15
    • 0040885457 scopus 로고
    • Abramovitch, R. A., Ed.; Plenum Press: New York
    • (b) Rappoport, Z. In Reactive Intermediates; Abramovitch, R. A., Ed.; Plenum Press: New York, 1983; Vol. 3, pp 427-615.
    • (1983) Reactive Intermediates , vol.3 , pp. 427-615
    • In, R.Z.1
  • 43
    • 0042872230 scopus 로고
    • Huyser, E. S., Ed.; Marcel Dekker: New York, Vols. 1-5.
    • (a) Methods in Free Radical Chemistry; Huyser, E. S., Ed.; Marcel Dekker: New York, 1969-1974; Vols. 1-5.
    • (1969) Methods in Free Radical Chemistry
  • 64
    • 0042863662 scopus 로고
    • Todres, Z. V. Tetrahedron 1987, 43, 3839; Acta Chem. Scand. 1990, 44, 535.
    • (1987) Tetrahedron , vol.43 , pp. 3839
    • Todres, Z.V.1
  • 69
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    • note
    • 44
  • 70
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    • Work in progress, in collaboration with the group of Prof. H. Lund, Arhus University, Denmark.
    • Work in progress, in collaboration with the group of Prof. H. Lund, Arhus University, Denmark.


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