Enantioselective Conjugate Addition of Grignard Reagents to Enones Catalyzed by Chiral Zinc(II) Complexes

Journal of Organic Chemistry

Volumn 55, Issue 13, 1990, Pages 4168-4175

  Jansen, Johan F G A ^a   Feringa, Ben L ^a  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000032365     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo00300a039     Document Type: Article

References (54)

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54. It is remarkable that in the enantioselective 1,2-additions of dialkylzinc reagents scrambling did occur when an amino alcohol ligand was used (involving tetracoordinated Zn(II))35and no scrambling was seen with a diamino alcohol ligand (involving pentacoordinated Zn(II)).