Structure and electrochemical properties of directly bound dinuclear cobaltadithiolene complexes. Substituent effect on reduction potentials and mixed-valence states

Bulletin of the Chemical Society of Japan

Volumn 71, Issue 10, 1998, Pages 2351-2358

  Akiyama, Takeo ^a   Amino, Masaki ^a   Saitou, Tsutomu ^a   Utsunomiya, Koutoku ^a   Seki, Ken Ichi ^a   Ikoma, Yoshiharu ^a   Kajitani, Masatsugu ^a   Sugiyama, Toru ^a   Shimizu, Kunio ^a   Sugimori, Akira ^a  

^a NONE

Author keywords

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EID: 0000030796     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.71.2351     Document Type: Article

References (35)

1. a) J.-P. Launay, S. Woitellier, M. Sowinska, M. Tourrel, and C. Joachim, in "Molecular Electronic Devices," ed by F. L. Carter, R. E. Siatkowski, and H. Wohltjen, Elservier Science Publishers, Amsterdam (1988), pp. 171-185;
2. b) P. Jutzi, U. Siemeling, A. Müller, and H. Bögge, Organometallics, 8, 1744 (1989);
3. M.-T. Lee, B. M. Foxman, and M. Rosenblum, Organometallics, 4, 539 (1985).
4. a) J. W. Park, P. B. Mackenzie, W. P. Schaefer, and R. H. Grubbs, J. Am. Chem. Soc., 108, 6402 (1986);
5. b) F. Ozawa, J. W. Park, P. B. Mackenzie, L. M. Henling, and R. H. Grubbs, J. Am. Chem. Soc., 111, 1319 (1989);
6. c) M. Darensburg, R. Silva, J. Reibenspies, and C. K. Prout, Organometallics, 8, 1315 (1989);
7. d) G. Süss-Fink, Angew. Chem., Int. Ed. Engl., 33, 67 (1994).
8. a) C. LeVanda, K. Bechgaard, D. O. Cowan, T. U. Mueller-Westerhoff, P. Eilbracht, G. Candela, and R. L. Collins, J. Am. Chem. Soc., 98, 3181 (1976);
9. b) C. LeVanda, K. Bechgaard, and D. O. Cowan, J. Org. Chem., 41, 2700 (1976);
10. c) E. E. Bunel, P. Campos, P. Ruz, L. Valle, I. Chadwick, M. S. Ana, G. Gonzalez, and J. M. Manriquez, Organometallics, 7, 474 (1988);
11. d) H. Atzkern, B. Huber, F. H. Köhler, G. Müller, and R. Müller, Organometallics, 10, 238 (1991);
12. 2] derivatives: R. Chukwu, A. D. Hunter, B. D. Santarsiero, S. G. Bott, J. L. Atwood, and J. Chassaignac, Organometallics, 11, 589 (1992);
13. f) D. O. Cowan, P. Shu, F. L. Hedberg, M. Rossi, and T. J. Kistenmacher, J. Am. Chem. Soc., 101, 1304 (1979);
14. g) D. C. O'Connor-Salazar and D. O. Cowan, J. Organomet. Chem., 408, 227 (1991).
15. a) R. Moulton, T. W. Weidman, K. P. C. Vollhardt, and A. J. Bard, Inorg. Chem., 25, 1846 (1986);
16. b) M.-H. Delville-Desbois, D. S. Brown, K. P. C. Vollhardt, and D. Astruc, J. Chem. Soc., Chem. Commun., 1991, 1355.
17. D. Obendort, H. Schottenberger, and C. Rieker, Organometallics, 10, 1293 (1991).
18. B. Bachmann, F. Hahn, J. Heck, and M. Wünsch, Organometallics, 8, 2523 (1989).
19. a) N. Van Order, Jr., W. E. Geiger, T. E. Bitterwolf, and A. L. Rheingold, J. Am. Chem. Soc., 109, 5680 (1987);
20. b) W. E. Geiger, N. Van Order, Jr., D. T. Pierce, T. E. Bitterwolf, A. L. Rheigold, and N. D. Chasteen, Organometallics, 10, 2403 (1991);
21. c) J. W. Merkert, J. H. Davis, Jr., W. E. Geiger, M. N. Paddon-Row, A. M. Oliver, and A. L. Rheingold, Organometallics, 11, 4109 (1992).
22. a) J. W. Merkert, J. H. Davis, Jr., W. E. Geiger, and R. N. Grimes, J. Am. Chem. Soc., 114, 9846 (1992);
23. b) J. Edwin, W. E. Geiger, and A. L. Rheingold, J. Am. Chem. Soc., 106, 3052 (1984).
24. H. Schimanke and R. Gleiter, Organometallics, 17, 275 (1998).
25. T. Akiyama, K. Nakamura, M. Tamada, H. Ushijima, M. Kajitani, K. Shimizu, and A. Sugimori, Chem. Lett., 1990, 1255.
26. a) M. Kajitani, T. Akiyama, A. Sugimori, K. Hirakata, Y. Hoshino, Y. Satsu, G. P. Sato, K. Shimizu, M. Kaise, and C. Nishihara, J. Electroanal. Chem., 251, 421 (1988);
27. b) H. Ushijima, M. Kajitani, K. Shimizu, G. P. Sato, T. Akiyama, and A. Sugimori, J. Electroanal. Chem., 303, 199 (1991).
28. M. Okubo, K. Aramaki, S. Nakajima, T. Watanabe, and H. Nishihara, Chem. Lett., 1995, 585.
29. D. Seyferth, M. O. Nestle, and A. T. Wehman, J. Am. Chem. Soc., 97, 7417 (1975).
30. C. Takayama, M. Kajitani, T. Sugiyama, and A. Sugimori, J. Organomet. Chem., in press.
31. An MM-2 calculation performed by using CAChe Mechanics system at TDK Co., Ltd. for 1d gives two stable conformations: The most stable conformation is the structure in which two phenyl groups are situated in the remote position and the second stable one is the conformation in which two phenyl groups are situated in parallel.
32. R. T. Boeré, B. Klassen, and K. H. Moock, J. Organomet. Chem., 467, 127 (1994).
33. T. Akiyama, Y. Watanabe, A. Miyasaka, T. Komai, H. Ushijima, M. Kajitani, K. Shimizu, and A. Sugimori, Bull. Chem. Soc. Jpn., 65, 1047 (1992).
34. p values were taken from this reference.
35. p value of le was calculated according to the following literature: M. Charton, J. Org. Chem., 28, 3121 (1963).