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Volumn 104, Issue 3, 1996, Pages 1067-1080

Characterization of solvent clusters in a supercritical Lennard-Jones fluid

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000021560     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.470762     Document Type: Article
Times cited : (45)

References (61)
  • 3
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    • Supercritical Fluids
    • edited by T. G. Squires and M. E. Paulaitis, ACS, Washington, DC
    • Supercritical Fluids, edited by T. G. Squires and M. E. Paulaitis, ACS Symposium Series 329 (ACS, Washington, DC, 1987).
    • (1987) ACS Symposium Series , vol.329
  • 4
    • 0000746640 scopus 로고
    • Supercritical Fluid Science and Technology
    • edited by K. P. Johnston and J. M. L. Penninger, ACS, Washington, DC
    • Supercritical Fluid Science and Technology, edited by K. P. Johnston and J. M. L. Penninger, ACS Symposium Series 406 (ACS, Washington, DC, 1989).
    • (1989) ACS Symposium Series , vol.406
  • 12
    • 85033045243 scopus 로고
    • Structure and Reactivity in Aqueous Solution, edited by D. G. Truhlar and C. J. Cramer ACS, Washington, DC
    • S. C. Tucker and E. M. Gibbons, in Structure and Reactivity in Aqueous Solution, ACS Symposium Series, edited by D. G. Truhlar and C. J. Cramer (ACS, Washington, DC, 1994).
    • (1994) ACS Symposium Series
    • Tucker, S.C.1    Gibbons, E.M.2
  • 16
    • 0346751196 scopus 로고
    • J. Am. Chem. Soc. 116, 2689 (1994).
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 2689
  • 48
    • 85033069783 scopus 로고    scopus 로고
    • note
    • 0 is too small to distinguish between large clusters and the small clusters of 2-3 atoms which occur in the cavity regions.
  • 49
    • 85033072546 scopus 로고    scopus 로고
    • note
    • c, consistent with the conclusion that the majority of cluster rearrangements occur by slow collective motions.
  • 51
    • 85033054438 scopus 로고    scopus 로고
    • av(t), and we have included the average atoms in the high density count for simplicity
    • av(t), and we have included the average atoms in the high density count for simplicity.
  • 57
    • 85033072453 scopus 로고    scopus 로고
    • note
    • It is conventional to define ξ in terms of the grand canonical distribution function ḡ(r), because it is only in this ensemble that ḡ(r), and thus ξ, is related to the isothermal compressibility through the compressibility equation (Ref. 51).
  • 58
    • 85033045590 scopus 로고    scopus 로고
    • x+
    • x+.
  • 59
    • 85033042763 scopus 로고    scopus 로고
    • The radial distribution functions are all step functions as a result of the design of the idealized system
    • The radial distribution functions are all step functions as a result of the design of the idealized system.
  • 60
    • 85033055546 scopus 로고    scopus 로고
    • For simplicity in the present discussion we neglect the presence of the average atoms as they do not appear in the partial distribution functions of interest
    • For simplicity in the present discussion we neglect the presence of the average atoms as they do not appear in the partial distribution functions of interest.
  • 61
    • 85033052421 scopus 로고    scopus 로고
    • note
    • lo, or N. This result will be valid given a sufficiently large initial canonical ensemble.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.