Formation of a Novel μ-Tetrasulfido-Bridged Dimer of a Dinuclear Platinum Complex

Inorganic Chemistry

Volumn 36, Issue 20, 1997, Pages 4296-4297

  Umakoshi, Keisuke ^a   Sasaki, Yoichi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000013389     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970848x     Document Type: Article

References (20)

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11. Experimental procedures and the physical properties of 2a,b are described in the Supporting Information.
12. 5+ is known to possess an intense blue color.
13. w) = 0.073 (0.086), GOF = 3.02. Selected bond lengths (Å) and angles (deg) for 2b: Pt1-Pt2 2.560(2), Pt3-Pt4 2.552(2), Pt1-Br1 2.705(5), Pt4-Br2 2.660(6), Pt2-S9 2.42(1), Pt3-S12 2.41(1), S9-S10 2.00(2), S10-S11 1.99(2), S11-S12 1.99(2), Br1-Pt1-Pt2 171.1(1), Pt1-Pt2-S9 174.4(3), Pt2-S9-S10 111.0(6), S9-S10-S11 109.6(7), S10-S11-S12 109.1(7), S11-S12-Pt3 109.9(6), S12-Pt3-Pt4 174.3(3), Pt3-Pt4-Br2 173.2(1). Full details for the crystallographic analysis of 2a,b are described in the Supporting Information.
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15. axial distances in 2a are shorter than the Pt-Cl distance in la.
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