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The list of rate constants is not meant to be exhaustive. We have omitted rate constants that were measured at relatively high temperatures (≈1000 K) such as those measured in shock tubes. Non-Arrhenius behavior is likely over the temperature range 298-1000 K. Therefore, extrapolation from 1000 to 298 K is likely to introduce some error. Reference 8 contains references to other TM + OX reactions at relatively high temperatures.
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