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Volumn 16, Issue 21, 1997, Pages 4675-4685

Electrochemical and IR/UV-Vis spectroelectrochemical studies of fac-[Mn(X)(CO)3(iPr-DAB)]n (n = 0, X = Br, Me, Bz; n = +1, X = THF, MeCN, nPrCN, P(OMe)3; iPr-DAB = 1,4-Diisopropyl-1,4-diaza-1,3-butadiene) at variable temperatures: Relation between electrochemical and photochemical generation of [Mn(CO)3(α-diimine)]-

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EID: 0000008044     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9702791     Document Type: Article
Times cited : (54)

References (67)
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    • note
    • -; OTTLE = optically transparent thin-layer electrochemical; SCE = saturated calomel electrode.
  • 37
    • 5644301046 scopus 로고    scopus 로고
    • note
    • -1).
  • 45
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    • Ph.D. Thesis, University of Amsterdam, Amsterdam, The Netherlands
    • (b) Nieuwenhuis, H. A. Ph.D. Thesis, University of Amsterdam, Amsterdam, The Netherlands, 1994.
    • (1994)
    • Nieuwenhuis, H.A.1
  • 47
    • 5644249402 scopus 로고    scopus 로고
    • note
    • -1).
  • 50
    • 5644294424 scopus 로고    scopus 로고
    • This assignment also corresponds with thin-layer cyclic voltammograms recorded in the course of the corresponding OTTLE experiments
    • This assignment also corresponds with thin-layer cyclic voltammograms recorded in the course of the corresponding OTTLE experiments.
  • 51
    • 5644295649 scopus 로고    scopus 로고
    • note
    • n (n = 0, X = Br; n = +1, X = MeCN, THF), as considered in the description of the reduction paths of the latter complexes.
  • 53
    • 85088224129 scopus 로고    scopus 로고
    • note
    • +.
  • 60
    • 85088230023 scopus 로고    scopus 로고
    • 3(iPr-DAB)] (X = Me, Bz) is localized on a LUMO possessing a predominant π*(iPr-DAB) character with a small contribution from the alkyl ligand
    • 3(iPr-DAB)] (X = Me, Bz) is localized on a LUMO possessing a predominant π*(iPr-DAB) character with a small contribution from the alkyl ligand.
    • Wilms, M.P.1


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